• 专利标题:   High-nickel ternary composite anode containing solid electrolyte useful in lithium ion battery field, comprises e.g. anode current collector and anode material layer e.g. anode active material, inorganic solid electrolyte and binder.
  • 专利号:   CN113363415-A, CN113363415-B, WO2022205668-A1
  • 发明人:   TIAN J, CHEN B, SU M, HAN X, LI F
  • 专利权人:   WANXIANG A123 SYSTEMS CORP, WANXIANG GROUP CORP, WANXIANG A123 SYSTEMS ASIA CO LTD, WANXIANG GROUP
  • 国际专利分类:   H01M010/0525, H01M004/131, H01M004/1391, H01M004/485, H01M004/505, H01M004/525, H01M004/62
  • 专利详细信息:   CN113363415-A 07 Sep 2021 H01M-004/131 202182 Pages: 12 Chinese
  • 申请详细信息:   CN113363415-A CN10335398 29 Mar 2021
  • 优先权号:   CN10335398

▎ 摘  要

NOVELTY - High-nickel ternary composite anode containing solid electrolyte comprises anode current collector and anode material layer set on the anode current collector; the anode material layer is formed by curing anode slurry containing anode active material, inorganic solid electrolyte, conductive agent and binder; the anode active material is high nickel cobalt manganese oxide complex (I) or high nickel cobalt aluminum oxide complex (II); inorganic solid electrolyte is lithium-lanthanum-zirconium oxide, lithium-germanium-phosphorus sulfur, (lithium oxide-aluminum oxide-silicon dioxide), (phosphorus pentoxide-titanium dioxide-germanium(IV) oxide), (lithium oxide-aluminum oxide-silicon dioxide-phosphorus pentoxide-titanium dioxide), lithium-lanthanum-zirconium-tantalum oxide, lithium-silicon-phosphorus-sulfur-chloride, lithium sulfide-phosphorus(V) sulfide, lithium oxide-phosphorus pentoxide, lithium-vanadium-germanium-oxide and/or lithium-zinc-germanium oxide. USE - The high-nickel ternary composite anode containing solid electrolyte is useful in lithium ion battery field (claimed). ADVANTAGE - The high nickel ternary composite anode: has both high energy density and high power density, and improved lithium-ion battery rate, high temperature storage and cycle performance while ensuring safety performance of battery to meet needs of power batteries. DETAILED DESCRIPTION - High-nickel ternary composite anode containing solid electrolyte comprises anode current collector and anode material layer set on the anode current collector; the anode material layer is formed by curing anode slurry containing anode active material, inorganic solid electrolyte, conductive agent and binder; the anode active material is high nickel cobalt manganese oxide complex of formula (LiNixCoyMnzO2) (I) or high nickel cobalt aluminum oxide complex of formula (LiNixCoyAlzO2) (II); inorganic solid electrolyte is lithium-lanthanum-zirconium oxide (Li7La3Zr2O12), lithium-germanium-phosphorus sulfur (Li10GeP2S12), (lithium oxide-aluminum oxide-silicon dioxide), (phosphorus pentoxide-titanium dioxide-germanium(IV) oxide), (lithium oxide-aluminum oxide-silicon dioxide-phosphorus pentoxide-titanium dioxide), lithium-lanthanum-zirconium-tantalum oxide (Li(6.75)La3Zr(1.75)Ta(0.25)O12), lithium-silicon-phosphorus-sulfur-chloride (Li(9.54)Si(1.74)P(1.44)S(11.7)Cl(0.3)), lithium sulfide-phosphorus(V) sulfide, lithium oxide-phosphorus pentoxide, lithium-vanadium-germanium-oxide (Li(3.5)V(0.5)Ge(0.5)O4) and/or lithium-zinc-germanium oxide (Li14ZnGe4O16). x = 0.6-1; y = 0-0.2; and x+y+z = 1.