• 专利标题:   Preparation of graphene used in e.g. gas absorption application, involves immersing refined coal powder in activating solution, carbonizing obtained molten mixture, acid-washing and water-washing obtained carbonized product, and drying.
  • 专利号:   WO2016184355-A1, KR2017141779-A, EP3299337-A1, CN107848805-A, US2018155201-A1, JP2018523623-W, EP3299337-A4
  • 发明人:   ZHANG Y
  • 专利权人:   ZHANG Y, KEY TEAM ENTERPRISES LTD, KEY TEAM ENTERPRISES LTD, KEY TEAM ENTERPRISES LTD, KEY TEAM ENTERPRISES LTD, ENN GRAPHENE TECHNOLOGY CO LTD
  • 国际专利分类:   C01B031/04, C01B032/184, C01B032/348, H01G011/26, H01G011/32, H01G011/44, H01G011/86, H01M004/587
  • 专利详细信息:   WO2016184355-A1 24 Nov 2016 C01B-031/04 201680 Pages: 31 Chinese
  • 申请详细信息:   WO2016184355-A1 WOCN081961 13 May 2016
  • 优先权号:   CN10257435, CN80026357, WOCN081961

▎ 摘  要

NOVELTY - Preparation of graphene involves refining coal or coal particles, immersing the obtained refined coal powders in an activating solution to obtain mixture of coal powder and activating solution, drying the above mixture to obtain a molten mixture of coal powder and activating solution, carbonizing the molten mixture in an atmosphere comprising inert gas or mixture of hydrogen and/or inert gas, and cooling the mixture to obtain a carbonized product, and acid-washing and water-washing the carbonized product, and drying above product to obtain porous graphene. USE - Preparation of graphene (claimed) used in gas absorption and separation, electrochemical energy storage and catalytic applications. ADVANTAGE - The method enables economical and easy preparation of microporous graphene with high yield and specific surface area. DETAILED DESCRIPTION - Preparation of graphene using coal as raw material involves refining coal or coal particles to obtain refined coal powders, immersing the refined coal powders in an activating solution and stirring for 10-36 hours at room temperature to obtain mixture of coal powder and activating solution, drying the above mixture to obtain a molten mixture of coal powder and activating solution, carbonizing the molten mixture in an atmosphere comprising inert gas or mixture of hydrogen and/or inert gas, and naturally cooling the mixture to obtain a carbonized product, and acid-washing and water-washing the carbonized product, and drying above product to obtain porous graphene.