• 专利标题:   Preparation of polyvinylidene fluoride hollow fiber membrane involves extruding polyvinylidene fluoride casting solution and functional material to form membrane with surface nano-functional layer, immersing in coagulation bath and curing.
  • 专利号:   CN112588131-A
  • 发明人:   ZHU L, FANG C, ZHOU Z, ZHOU L
  • 专利权人:   HANGZHOU GAOTONG MEMBRANE TECHNOLOGY CO
  • 国际专利分类:   B01D067/00, B01D069/08
  • 专利详细信息:   CN112588131-A 02 Apr 2021 B01D-069/08 202143 Pages: 11 Chinese
  • 申请详细信息:   CN112588131-A CN11574088 28 Dec 2020
  • 优先权号:   CN11574088

▎ 摘  要

NOVELTY - Preparation of nanocomposite polyvinylidene fluoride hollow fiber membrane involves dissolving 15-40 wt.% polyvinylidene fluoride resin and 5-20 wt.% additive in 40-80 wt.% solvent or diluent, defoaming to form polyvinylidene fluoride casting solution, dispersing 0.5-20 wt.% nano-functional material in 0.5-5 wt.% polyvinylidene fluoride solution to obtain nano-functional material solution, using three-layer channel spinneret as co-extrusion equipment, extruding the casting solution through middle channel of extruder to form hollow fiber membrane component, extruding nano-functional material solution through outer channel to form surface nano-functional layer on hollow fiber membrane, using inner channel to extrude core liquid, gas or reinforcing material to form inner cavity of hollow fiber membrane, immersing polyvinylidene fluoride hollow fiber membrane component with surface nano-functional layer in coagulation bath at -20 degrees C to 60 degrees C for phase conversion and curing. USE - Preparation of nanocomposite polyvinylidene fluoride hollow fiber membrane. ADVANTAGE - The preparation method adopts co-extrusion and modification process without affecting the performance of the membrane flux and solute retention, and produces hollow fiber membrane with surface composite nano-functional layer, which is not easy to peel off, and exhibits excellent stability and modification effect. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for co-extrusion equipment.