• 专利标题:   Preparation of graphene-silicon nitride hybrid aerogel for forming epoxy resin-based composite material, involves hydrothermally reducing aminated silicon nitride whisker, graphene oxide, reducing agent and water, and freeze drying.
  • 专利号:   CN114835952-A, CN114835952-B
  • 发明人:   ZHAO X, JIANG W, LI P, CHU F, YANG M, WANG W, ZHANG Z, YUAN J
  • 专利权人:   LANZHOU CHEM PHYSICS INST CHINESE ACAD
  • 国际专利分类:   C01B032/19, C01B032/194, C08K003/04, C08K007/10, C08K007/24, C08K009/10, C08L063/00
  • 专利详细信息:   CN114835952-A 02 Aug 2022 C08K-009/10 202200 Chinese
  • 申请详细信息:   CN114835952-A CN10384401 13 Apr 2022
  • 优先权号:   CN10384401

▎ 摘  要

NOVELTY - Preparation of graphene-silicon nitride hybrid aerogel involves (i) mixing silicon nitride whisker, dopamine hydrochloride and polyethyleneimine in a tris-hydrochloride buffer solution for amination modification reaction to obtain aminated silicon nitride whiskers, (ii) mixing the aminated silicon nitride whisker, graphene oxide, a reducing agent and water to perform a hydrothermal reduction reaction to obtain graphene-silicon nitride hybrid hydrogel, and (iii) freeze drying the obtained hydrogel. USE - Preparation of graphene-silicon nitride hybrid aerogel used for forming epoxy resin-based composite material (claimed). ADVANTAGE - The method produces aerogel having excellent lubricating property, synergistic effect, and produces epoxy resin-based composite material having excellent tribology performance, anti-friction and wear-resistant properties. The silicon nitride whisker is anchored in the graphene aerogel, suppresses the silicon nitride whisker agglomeration in the epoxy resin, and further improves the three-dimensional heat conduction network in the epoxy resin. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) graphene-silicon nitride hybrid aerogel, which comprises gel porous network structure constructed by graphene nanosheets and silicon nitride whisker anchored in the three-dimensional porous network structure. The surface of silicon nitride whiskers is coated with polydopamine-polyethyleneimine copolymer; (2)epoxy resin-based composite material, which comprises the graphene-silicon nitride hybrid aerogel and an epoxy resin cured product filled in the aerogel; and (3)manufacture of epoxy resin-based composite material, which involves mixing epoxy resin and a curing agent for pre-curing to obtain pre-cured liquid and immersing the graphene-silicon nitride hybrid aerogel into the pre-cured liquid for vacuum impregnation, and curing the impregnated graphene-silicon nitride hybrid aerogel.