• 专利标题:   Preparation of polyamidoxime/graphene nanoribbon composite aerogel as adsorbent for separation and enrichment of uranium, by adding graphene oxide nanoribbons to mixed solution of acrylonitrile and ammonium persulfate, and polymerizing.
  • 专利号:   CN111484644-A
  • 发明人:   WANG Y, LI Y, WU Z, HE H, HU X, LIU Z, TU H, LIU Y, YUAN D
  • 专利权人:   UNIV EAST CHINA TECHNOLOGY
  • 国际专利分类:   B01J020/26, B01J020/28, B01J020/30, C01B032/198, C08F220/44, C08F292/00, C08F008/00, C08J009/28, C08L051/10, G21F009/12
  • 专利详细信息:   CN111484644-A 04 Aug 2020 C08J-009/28 202070 Pages: 14 Chinese
  • 申请详细信息:   CN111484644-A CN10304846 17 Apr 2020
  • 优先权号:   CN10304846

▎ 摘  要

NOVELTY - Preparation of polyamidoxime/graphene nanoribbon composite aerogel involves: axially cutting multi-walled carbon nanotubes into graphene oxide nanoribbons by using potassium permanganate oxidation method; then adding to a mixed solution of acrylonitrile and ammonium persulfate, and preliminarily making polyacrylonitrile/graphene nanoribbons composite hydrogels by solvothermal polymerization method; and using cyano and hydroxylamine to convert the cyano group into an amidoxime group under alkaline conditions to obtain polyamidoxime/graphene nanoribbon composite hydrogel, and finally carrying out low-temperature freeze-drying. USE - The method is useful for preparing polyamidoxime/graphene nanoribbon composite aerogel, which is useful as adsorbent for separation and enrichment of uranium (claimed). ADVANTAGE - The polyamidoxime/graphene nanoribbon composite aerogel: has high grafting rate, uniform density distribution and stable structural performance; and is rich in uranium-specific functional groups, which can be effectively and selectively remove uranium from different uranium-containing water components. The adsorbed aerogel can be quickly separated and recovered from the solid-liquid system without pollution to the environment. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for separating and enriching uranium by using the polyamidoxime/graphene nanoribbon composite aerogel.