• 专利标题:   Three-layer anticorrosive high-strength coating comprises conductive base layer including polyaniline modified graphene, elastic middle layer including liquid crystal microcapsules and surface nano-modified layer.
  • 专利号:   CN112011252-A
  • 发明人:   FAN R
  • 专利权人:   DONGGUAN HUMA COMMERCE TRADE CO LTD
  • 国际专利分类:   B05D001/06, B05D003/02, B05D005/00, B05D007/00, B05D007/24, C09D163/00, C09D167/00, C09D005/03, C09D005/08, C09D005/24, C09D005/46, C09D007/40, C09D007/62
  • 专利详细信息:   CN112011252-A 01 Dec 2020 C09D-163/00 202004 Pages: 10 Chinese
  • 申请详细信息:   CN112011252-A CN10894538 31 Aug 2020
  • 优先权号:   CN10894538

▎ 摘  要

NOVELTY - A three-layer anticorrosive high-strength coating comprises a conductive base layer, an elastic middle layer and a surface nano-modified layer. The conductive base layer, elastic intermediate layer and surface nano-modified layer are respectively obtained from conductive base powder, elastic intermediate layer powder and surface nano-modified layer powder through electrostatic spraying and heat treatment. The conductive base layer powder includes polyaniline modified graphene. The elastic intermediate layer powder includes liquid crystal microcapsules. The surface layer nano-modified layer powder includes siloxane-modified nano silica. USE - Three-layer anticorrosive high-strength coating. ADVANTAGE - The method enables formation of three-layer coating with excellent anticorrosive property and high strength. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for manufacture of three-layer anticorrosive high-strength coating, which involves (i) adding graphene to the alkaline solution of phenylenediamine, heating and stirring the reaction, adjusting the system to acidity, adding aniline and initiator, stirring the reaction at low temperature, filtering and washing freeze-dry to obtain polyaniline modified graphene, adding polyaniline modified graphene to epoxy resin powder coating to prepare conductive base layer powder, (ii) adding triglycidyl isocyanurate curing agent to the polymethyl methacrylate solution containing liquid crystals, stirring evenly at room temperature, and adding sodium dodecylbenzene sulfonate aqueous solution, quickly stirring and emulsifying, heating under reduced pressure to evaporate the solvent to obtain liquid crystal microcapsules, and adding the liquid crystal microcapsules to epoxy resin powder coating to prepare elastic intermediate layer powder, (iii) adding the siloxane-modified nano-silica particles into the epoxy resin powder coating to prepare surface layer nano-modified layer powder, and (iv) after cleaning the surface of the substrate, electrostatically spraying and heat treating the conductive base layer powder prepared in step (i), the elastic intermediate layer powder prepared in step (ii) and the surface nano-modified layer powder prepared in step (iii).