• 专利标题:   Phosphorus-doped graphene oxide redox electrocatalyst useful as e.g. electrode material of lithium ion battery comprises graphene oxide substrate and reactive phosphorus element doped or attached on carbon skeleton of substrate.
  • 专利号:   CN103495430-A
  • 发明人:   LI R, GOU X
  • 专利权人:   UNIV CHINA WEST NORMAL
  • 国际专利分类:   B01J027/14, H01M004/90
  • 专利详细信息:   CN103495430-A 08 Jan 2014 B01J-027/14 201418 Pages: 11 Chinese
  • 申请详细信息:   CN103495430-A CN10485468 16 Oct 2013
  • 优先权号:   CN10485468

▎ 摘  要

NOVELTY - Phosphorus-doped graphene oxide redox electrocatalyst comprises graphene oxide substrate and reactive phosphorus element doped or attached on carbon skeleton of graphene oxide substrate. USE - The catalyst is useful: as a fuel battery and metal-air battery cathode electrodeposition catalyst; as an electrode material for lithium ion battery, sodium ion battery, super capacitor, electrochemical energy storage and conversion device; and in electrochemical sensors and biosensors (all claimed). ADVANTAGE - The electrocatalyst has high catalytic activity. The method is free of methanol and carbon monoxide poisoning; and has high stability. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing the catalyst, comprising (a) preparing graphite oxide using colloidal graphite, carrying out Hummer method to prepare graphite oxide, (b) uniformly mixing graphite oxide and phosphorus-containing ionic liquid in a mass ratio of 1:1, ultrasonically dispersing graphite oxide in the phosphorus-containing ionic liquid (ethanol solution of 1-butyl-3-methylimidazolium hexafluorophosphate (BmimPF6)), (c) drying the dispersion liquid in an oven at 45 degrees C for 24 hours under vacuum, and (d) transferring the dried mixture into an inert atmosphere, processing at 200-1000 degrees C.