• 专利标题:   Production of graphene/polyvinyl alcohol-modified nonwoven fabric used for e.g. clothes, involves dipping nonwoven fabric in graphene oxide/polyvinyl alcohol modification solution, drying, placing in hydroiodic acid solution and drying.
  • 专利号:   CN105002736-A, CN105002736-B
  • 发明人:   CHEN S, DUAN N, WANG H, WU J, WANG L, YIN X
  • 专利权人:   UNIV WUHAN TEXTILE
  • 国际专利分类:   D06M101/20, D06M101/22, D06M101/28, D06M101/30, D06M101/32, D06M101/34, D06M011/74, D06M015/333
  • 专利详细信息:   CN105002736-A 28 Oct 2015 D06M-015/333 201632 Pages: 11 Chinese
  • 申请详细信息:   CN105002736-A CN10393308 07 Jul 2015
  • 优先权号:   CN10393308

▎ 摘  要

NOVELTY - Production of graphene/polyvinyl alcohol-modified nonwoven fabric involves dispersing graphene oxide in distilled water, ultrasonically-treating, obtaining 3-30 mg/mL graphene oxide dispersion, adding soluble polyvinyl alcohol to the resultant product, stirring, obtaining graphene oxide/polyvinyl alcohol composite modification solution, dipping nonwoven fabric in the obtained solution, drying the nonwoven fabric, placing the resultant product in hydroiodic acid solution, drying, such that graphene oxide on the surface of nonwoven fiber is reduced, washing, and drying. USE - Production of graphene/polyvinyl alcohol-modified nonwoven fabric used for clothes, home-use textiles, medical health care applications, air purification applications, sewage treatment applications and military applications. ADVANTAGE - The method enables simple and economical production of graphene/polyvinyl alcohol-modified nonwoven fabric having excellent hydrophilic property, antibiotic property, antistatic property and adsorptive function. DETAILED DESCRIPTION - Production of graphene/polyvinyl alcohol-modified nonwoven fabric involves dispersing graphene oxide in distilled water, ultrasonically-treating, obtaining 3-30 mg/mL graphene oxide dispersion, adding soluble polyvinyl alcohol having molecular weight of 1700-100000 to the resultant product, stirring, obtaining graphene oxide/polyvinyl alcohol composite modification solution having polyvinyl alcohol content of 4-16 %mass, and mass ratio of graphene oxide and polyvinyl alcohol of 5:95-80:20, dipping nonwoven fabric in the obtained solution, drying the nonwoven fabric, placing the resultant product in hydroiodic acid solution, drying, such that graphene oxide on the surface of nonwoven fiber is reduced, washing obtained nonwoven fabric with distilled water and ethanol, and drying. The nonwoven fabric is polypropylene, polyester, polyethylene, nylon, acrylic resin, polytetrafluoroethylene, polyvinyl chloride or polyphenylene sulfide. The hydroiodic acid solution comprises aqueous solution of hydroiodic acid or hydroiodic acid/acetic acid solution.