• 专利标题:   Preparation of cobalt-nickel-tungsten alloy oxide-graphene composite material for electrode material, involves dripping sodium borohydride solution to graphene oxide solution, adding powder to hydrogen peroxide and oxidizing mixture.
  • 专利号:   CN106504905-A, CN106504905-B
  • 发明人:   ZOU Y, CAI C, XIANG C, XU F, SUN L
  • 专利权人:   UNIV GUILIN ELECTRONIC TECHNOLOGY, UNIV GUILIN ELECTRONIC TECHNOLOGY
  • 国际专利分类:   H01G011/24, H01G011/30, H01G011/36, H01G011/46, H01G011/86
  • 专利详细信息:   CN106504905-A 15 Mar 2017 H01G-011/24 201730 Pages: 7 Chinese
  • 申请详细信息:   CN106504905-A CN11016365 18 Nov 2016
  • 优先权号:   CN11016365

▎ 摘  要

NOVELTY - Graphene oxide is added to acetonitrile solution and dispersed. Cobalt sulfate, nickel sulfate and sodium tungstate are added to acetonitrile solution and stirred. The acetonitrile solution is dispersed. Sodium borohydride is weighed, and water is added to mixture, to obtain sodium borohydride aqueous solution. Aqueous sodium borohydride solution is dripped to acetonitrile solution, reacted, filtered, washed, and dried, to obtain powder. Powder is added to hydrogen peroxide and oxidized, to obtain flower-like cobalt-nickel-tungsten alloy oxide-graphene composite. USE - Preparation of cobalt-nickel-tungsten alloy oxide-graphene composite material used for electrode material of supercapacitor (claimed). ADVANTAGE - The method enables preparation of three-dimensional flower-shaped cobalt-nickel-tungsten alloy oxide-graphene composite material with excellent electrochemical property and high yield. DETAILED DESCRIPTION - Predetermined amount of graphene oxide is added to acetonitrile solution and ultrasonically dispersed for 1 hour. Predetermined amount of cobalt sulfate, nickel sulfate and sodium tungstate are added to acetonitrile solution and stirred. The acetonitrile solution is placed in ultrasonic cleaner and ultrasonically dispersed. Predetermined amount of sodium borohydride is weighed, and water is added to mixture, to obtain sodium borohydride aqueous solution. Aqueous sodium borohydride solution is dripped to acetonitrile solution, reacted for 2 hours, filtered, washed, and dried, to obtain powder. Powder is added to 5-10 mL hydrogen peroxide and oxidized, to obtain flower-like cobalt-nickel-tungsten alloy oxide-graphene composite. An INDEPENDENT CLAIM is included for usage of cobalt-nickel-tungsten alloy oxide-graphene composite material for electrode of supercapacitor.