• 专利标题:   Preparation of lithium sulfur battery anode material involves adding graphene oxide to template material, dispersing, spray-drying, reducing, etching with hydrofluoric acid, adding nano sulfur powder, milling, heating, and melting.
  • 专利号:   CN106981649-A, CN106981649-B
  • 发明人:   LI H, SUN L, YANG S, WANG Z, LIU W, LIU F, CAO H
  • 专利权人:   UNIV HEBEI TECHNOLOGY, UNIV HEBEI TECHNOLOGY
  • 国际专利分类:   H01M010/052, H01M004/36, H01M004/38, H01M004/62
  • 专利详细信息:   CN106981649-A 25 Jul 2017 H01M-004/36 201758 Pages: 14 Chinese
  • 申请详细信息:   CN106981649-A CN10416270 06 Jun 2017
  • 优先权号:   CN10416270

▎ 摘  要

NOVELTY - Preparation of lithium sulfur battery anode material comprises preparing graphene oxide by using improved Hummers method; adding 1-10 mg/mL first water solution and 1-100 mg/mL 10-300 nm silicon dioxide balls as template material , mixing, ultrasonically dispersing for 1-5 hours at 300-650 W, magnetically stirring, spray-drying at 30-100 degrees C, reducing at 150-250 degrees C, soaking in 5-40% hydrofluoric acid for 6-24 hours, and etching; and adding pure phase nano sulfur powder at ratio of 1:1-10, ball milling for 2-4 hours, heat treating and melting at 100-200 degrees C for 8-12 hours. USE - Method for preparing lithium sulfur battery anode material (claimed). ADVANTAGE - The method overcomes low quantity effective load of sulfur in lithium-sulfur battery anode material, volume expansion effect, and instable electrochemical performance. DETAILED DESCRIPTION - Preparation of lithium sulfur battery anode material comprises preparing graphene oxide by using improved Hummers method; adding 1-10 mg/mL first water solution and 1-100 mg/mL 10-300 nm silicon dioxide balls as template material at ratio of 1:1-10, mixing, ultrasonically dispersing for 1-5 hours at 300-650 W, magnetically stirring, spray-drying at 30-100 degrees C, reducing at 150-250 degrees C, soaking in 5-40% hydrofluoric acid for 6-24 hours, and etching; and adding pure phase nano sulfur powder at ratio of 1:1-10, ball milling for 2-4 hours at 100-500 revolutions/minute, heat treating and melting at 100-200 degrees C for 8-12 hours.