• 专利标题:   Preparation of aromatic nitrile graphene involves hydrolyzing nitrile graphene crystallites, heating, filtering, washing carbon solids, heating resultant product, and reacting with acetic acid, ammonia and acetyl hydrazine.
  • 专利号:   CN105622454-A, CN105622454-B
  • 发明人:   LI X
  • 专利权人:   LI X
  • 国际专利分类:   C01B031/04, C07C231/10, C07C231/12, C07C237/22, C08G069/00
  • 专利详细信息:   CN105622454-A 01 Jun 2016 C07C-237/22 201675 Pages: 8 Chinese
  • 申请详细信息:   CN105622454-A CN10990985 25 Dec 2015
  • 优先权号:   CN10990985

▎ 摘  要

NOVELTY - Nitrile graphene crystallites are mixed with deionized water, hydrolyzed, heated and cooled to 40 degrees C. To the resultant mixture, hydrazine hydrate is added, filtered and resultant carbon solids are washed using alcohol solvent. The washed product is then added to a reactor, heated, and acetic acid, ammonia and acetyl hydrazine are added and reacted to obtain aromatic nitrile graphene. USE - Preparation of aromatic nitrile graphene (claimed). DETAILED DESCRIPTION - Acetic acid and aqueous ammonia are subjected to molecular sieve synthesis column, and processed out to obtain adiponitrile. Obtained adiponitrile, hydrogen, carbon dioxide and water are subjected to vapor-phase synthesis reaction to obtain adiponitrile oily liquid which is then cooled and hydrogen is collected. Adiponitrile is added to nickel acetate, and reacted to obtain caprolactam. Caprolactam is added to palladium acetate, and collected hydrogen is introduced and aromatization reaction is carried out to obtain nitrile graphene crystallites. Nitrile graphene crystallites are mixed with deionized water, hydrolyzed, heated and cooled to 40 degrees C. To the resultant mixture, hydrazine hydrate is added, filtered and resultant carbon solids are washed using alcohol solvent. The washed product is then added to a reactor, heated, and acetic acid, ammonia and acetyl hydrazine are added and reacted to obtain aromatic nitrile graphene.