• 专利标题:   Metal organic framework material and two-dimensional material composite useful in sewage treatment, comprises ferrocene-based metal-organic framework materials supported on graphitic carbon nitride with two-dimensional sheet structure.
  • 专利号:   CN114082445-A
  • 发明人:   WANG L, HUANG Z, YU H
  • 专利权人:   UNIV ZHEJIANG
  • 国际专利分类:   B01J027/24, B01J031/22, C02F001/30, C02F001/72, C02F101/30, C02F101/32, C02F101/34, C02F101/36, C02F101/38
  • 专利详细信息:   CN114082445-A 25 Feb 2022 B01J-031/22 202261 Chinese
  • 申请详细信息:   CN114082445-A CN11355354 16 Nov 2021
  • 优先权号:   CN11355354

▎ 摘  要

NOVELTY - Metal organic framework material and two-dimensional material composite comprises ferrocene-based metal-organic framework materials supported on graphitic carbon nitride with two-dimensional sheet structure. The ferrocene-based metal-organic framework material is metal-organic framework material modified with ferrocene. USE - The ferrocene-modified Uio-66-amino-X supported on graphitic carbon nitride-Y composites is useful in sewage treatment (claimed). ADVANTAGE - The ferrocene-modified metal-organic framework is loaded on the graphitic carbon nitride composite material, which prevents the agglomeration of the nanoparticles of the metal-organic framework material, improves the transmission efficiency of photogenerated carriers; and has excellent sewage treatment performance. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing the metal organic framework material, comprising (S1) taking ferrocene-modified Uio-66-amino-X and ultrasonically dispersing it in a solvent to obtain a uniform dispersion A after ultrasonic treatment at room temperature, taking the graphite phase carbon nitride and ultrasonically dispersing it in solvent to obtain a uniform dispersion B after ultrasonic treatment at room temperature, (S2) adding polyethylene glycol solution with a mass fraction of 5% to dispersion A to obtain dispersion C, (S3) mixing dispersion A and dispersion C, and stirring to obtain uniform dispersion D, and (S4) adding uniform dispersion D into the lining of the reactor and sealing, and reacting at 100degrees Celsius for 1-48 hours to obtain composite material of ferrocene-modified Uio-66-amino-X supported on graphitic carbon nitride-Y.