• 专利标题:   Coating graphene filter membrane material with enhanced hydrophilicity, comprises e.g. performing Michael addition reaction under alkaline conditions, and grafting polymer on graphene filter membrane material containing dopamine.
  • 专利号:   CN111318185-A
  • 发明人:   WANG X, HAN Z, LIU L, XIU C, YUAN X, CHEN C, QU Y
  • 专利权人:   CHINA PETROLEUM CHEM CORP, SINOPEC SHENGLI OILFIELD TECHNOLOGY TEST
  • 国际专利分类:   B01D067/00, B01D071/62, C02F001/44, C08F220/28, C08F008/00
  • 专利详细信息:   CN111318185-A 23 Jun 2020 B01D-071/62 202059 Pages: 10 Chinese
  • 申请详细信息:   CN111318185-A CN11544409 17 Dec 2018
  • 优先权号:   CN11544409

▎ 摘  要

NOVELTY - Coating graphene filter membrane material with enhanced hydrophilicity, comprises performing Michael addition reaction under alkaline conditions, and grafting the polymer P (MeO2MA-co-OEGMA-SH) on the graphene filter membrane material containing dopamine to form a super-hydrophilic graphene filter membrane material. USE - The method is useful for coating graphene filter membrane material with enhanced hydrophilicity. ADVANTAGE - The method: utilizes dopamine hydrothermal reduction of graphene to obtain porous polydopamine-graphene gel; has high oil-water separation efficiency; is simple, easy to implement, and economical; has wide in application range, and broad application prospects. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing polymer P (MeO2MA-co-OEGMA-SH) using the enhanced hydrophilic graphene filter membrane material, comprising adding 2-methyl-2 acrylic acid-2(2 methoxyethoxy) ethyl ester, using oligoethylene glycol methyl ether methacrylate as monomers, double (2-(2'-bromoisobutyryloxy)ethyl) disulfide as initiator, cuprous bromide as catalyst, 2,2'-bipyridine as ligand, and P(MEO2MA-co-OEGMA-SS-MEO2MA-co-OEGMA) as copolymer, and using tributylphosphine as a reduction catalyst to break the disulfide bond in the P(MEO2MA-co-OEGMA-SS-MEO2MA-co-OEGMA) copolymer to obtain the polymer P(MeO2MA-co-OEGMA-SH).