• 专利标题:   Preparing graphene molybdenum disulfide-ferric oxide complex by carbohydrate organic carbon reduction comprises adding the molybdenum disulfide powder in the intercalation solution carrying out intercalation reaction.
  • 专利号:   CN106564963-A, CN106564963-B
  • 发明人:   HU P, WANG K, CHEN Z, ZHOU Y, DENG J, YANG F, HU B, LI Q, CHANG T, LIU M
  • 专利权人:   UNIV XIAN ARCHITECTURE TECHNOLOGY
  • 国际专利分类:   B82Y030/00, C01G039/06, C01G049/08
  • 专利详细信息:   CN106564963-A 19 Apr 2017 C01G-049/08 201738 Pages: 19 Chinese
  • 申请详细信息:   CN106564963-A CN10965684 04 Nov 2016
  • 优先权号:   CN10965684

▎ 摘  要

NOVELTY - Preparing graphene molybdenum disulfide-ferric oxide complex by carbohydrate organic carbon reduction comprises (i) adding the molybdenum disulfide powder in the intercalation solution carrying out intercalation reaction, filtering, drying to obtain intercalated molybdenum disulfide powder, the intercalation solution is potassium chlorate, sodium nitrate or the mixed solution of concentrated sulfuric acid and hydrogen peroxide. USE - The method is useful for preparing graphene molybdenum disulfide-ferric oxide complex by carbohydrate organic carbon reduction (claimed). DETAILED DESCRIPTION - Preparing graphene molybdenum disulfide-ferric oxide complex by carbohydrate organic carbon reduction comprises (i) adding the molybdenum disulfide powder in the intercalation solution carrying out intercalation reaction, filtering, drying to obtain intercalated molybdenum disulfide powder, the intercalation solution is potassium chlorate, sodium nitrate or the mixed solution of concentrated sulfuric acid and hydrogen peroxide, the ratio of the molybdenum disulfide powder, potassium chlorate, sodium nitrate, 98% concentrated sulfuric acid and 30% hydrogen peroxide is 1 g:1-4 g: 0.5-2g:9-40ml:4-20 ml, (ii) mixing obtain intercalated molybdenum disulfide powder and carbohydrate organic carbon and water, stirring uniformly, drying and grinding to obtain the precursor powder, the ratio of intercalated molybdenum disulfide powder and organic carbon and water is 2 g:0.24-1.2g:10-30g, (iii) mixig ferric nitrate and citric acid into water, chelating to obtain sol-gel solution, the ratio of ferric nitrate, citric acid and deionized water is 1 g:0.8-1.2g:1-3g, (iv) adding precursor powder to the sol solution, stirring and mixing to obtain the mixed gel, drying, grinding to obtain the dry gel powder, the ratio of sol solution and precursor powder is 100 g:1.7-5.5 g, (v) reacting gel powder, reducing under protective gas, cooling and grinding to obtain the product.