• 专利标题:   Noble metal platinum nano catalyst useful for high temperature reaction comprises noble metal platinum particle loaded on the transition metal iron oxide, simultaneously graphene oxide as both integral substrate dispersed uniformly.
  • 专利号:   CN105964274-A, CN105964274-B
  • 发明人:   DAI Y, QI X, WU D, FU W, SUN Y
  • 专利权人:   UNIV SOUTHEAST, UNIV SOUTHEAST
  • 国际专利分类:   B01J023/89
  • 专利详细信息:   CN105964274-A 28 Sep 2016 B01J-023/89 201682 Pages: 12 Chinese
  • 申请详细信息:   CN105964274-A CN10397435 07 Jun 2016
  • 优先权号:   CN10397435

▎ 摘  要

NOVELTY - Noble metal platinum nano catalyst comprises noble metal platinum particle loaded on the transition metal iron oxide, simultaneously graphene oxide as both integral substrate dispersed uniformly. USE - The catalyst is useful for not less than 750 degrees C under conditions using high temperature catalyst (claimed), automobile exhaust treatment and other high-temperature reactions. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing noble metal platinum nano catalyst, comprising (i) using polyol reduction method obtaining 3-5 nm platinum particles, where the platinum material is chloroplatinic acid hexahydrate, reducing agent is ethylene glycol, the surfactant is polyvinyl pyrrolidone, (ii) using electrostatic spinning technology obtaining tris(acetylacetonato) iron(III)/polyvinyl pyrrolidone composite nano fiber, comprising tris(acetylacetonato) iron(III)/polyvinyl pyrrolidone composite fiber as raw material, dissolving in acetic acid aqueous solution of pH 2-3, carrying out hydrothermal reaction for 5-12 hours at 120-200 degrees C, obtained product is hematite, washing with water and ethanol, dispersing in ethanol, (iii) dispersing 3-5 nm platinum particles on the carrier hematite by simple dipping method to obtain catalyst precursor platinum/iron oxide, where the weight ratio of platinum and iron oxide in the catalyst is 1:100-1:200, (iv) dispersing step (iii) catalytic precursor platinum/iron oxide in 6 mg/ml polyvinyl pyrrolidone (Mw about 55000) ethanol solution, using vortex mixer obtaining suspension, (v) using dipping method dispersing catalytic precursor platinum/iron oxide suspension on the surface of graphene oxide, where the catalyst iron oxide with the weight ratio of the graphite oxide is 1:6-1:30, preparing plant transpiration inhibiting material with noble metal platinum nano-catalyst of strong anti-sintering performance.