• 专利标题:   Preparing graphene oxide coated ZIF-67 derived iron/cobalt/nitrogen/co-doped porous carbon nano-particle composite material, comprises e.g. taking cobalt nitrate hexahydrate and ferric nitrate dissolved in methanol solution.
  • 专利号:   CN114204048-A
  • 发明人:   LIN J, XIONG J, CHEN X
  • 专利权人:   UNIV NORTH CHINA ELECTRIC POWER
  • 国际专利分类:   H01M004/86, H01M004/88, H01M004/90
  • 专利详细信息:   CN114204048-A 18 Mar 2022 H01M-004/88 202232 Chinese
  • 申请详细信息:   CN114204048-A CN11415299 25 Nov 2021
  • 优先权号:   CN11415299

▎ 摘  要

NOVELTY - Preparing graphene oxide coated zeolite imidazolate framework (ZIF-67) derived iron/cobalt/nitrogen/co-doped porous carbon nano-particle composite material, comprises (i) dissolving cobalt nitrate hexahydrate and ferric nitrate in methanol solution, stirring, adding graphene oxide suspension and continuously stirring to obtain the first mixed solution; (ii) taking dimethyl imidazole dissolved in methanol solution and stirring to obtain the second mixed solution;(iii) pouring the second mixed solution into the first mixed solution under the stirring condition and stirring to obtain the purple suspension; (iv) separating the obtained purple suspension liquid, drying, introducing into a tubular quartz furnace, heating and carbonizing under the protection of inert gas, cooling, to obtain the target product. USE - The material is useful for fuel cell cathode catalyst (claimed). ADVANTAGE - The composite material has excellent electrochemical performance, high initial potential, half-wave potential, high limit current density, excellent stability and anti-methanol performance. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for graphene oxide coated zeolite imidazolate framework (ZIF-67) derived iron/cobalt/nitrogen/co-doped porouscarbon nano-particle composite material.