• 专利标题:   Preparation of graphene stock solution for producing nanofibers, involves reacting graphite powder, hydrogen peroxide, high-potassium powder, potassium permanganate and chlorine gas, ultrasonically vibrating, centrifuging and washing.
  • 专利号:   CN108483434-A
  • 发明人:   CUI J
  • 专利权人:   ZHONGHONG NANOFIBER TECHNOLOGY DANYANG
  • 国际专利分类:   C01B032/198, D01F001/09, D01F001/10
  • 专利详细信息:   CN108483434-A 04 Sep 2018 C01B-032/198 201868 Pages: 8 Chinese
  • 申请详细信息:   CN108483434-A CN10327483 12 Apr 2018
  • 优先权号:   CN10327483

▎ 摘  要

NOVELTY - The preparation of graphene stock solution for producing nanofibers, involves (1) mixing graphite powder and strong oxidizing mixture at mass ratio of 1:3, stirring and leaving the mixture still for 1 hour to obtain solution (A), (2) adding hydrogen peroxide to solution (A) and mixing well, the volume ratio of solution (A) and hydrogen peroxide is 7:5, and stirring for 30-60 minutes at rate of 110 rpm, leaving the mixture still for 2-3 hours to obtain solution (B), (3) adding high-potassium powder to solution (B), the mass ratio of solution (B) and potassium permanganate is 3:1, stirring for 25-55 minutes at 45-50 degrees C at rate of 135 rpm, ultrasonically vibrating for 30-40 minutes with frequency of 40-60 kHZ to obtain solution (C), (4) introducing chlorine gas into solution (C), and the volume ratio of solution (C) and chlorine gas is 10:13, reacting for 30-90 minutes and leaving still for 2 hours, ultrasonically vibrating, centrifuging and washing lower layer with deionized water. USE - Preparation of graphene stock solution for producing nanofibers. ADVANTAGE - The method enables preparation of graphene stock solution ensuring high production efficiency by simple and easy process. DETAILED DESCRIPTION - The preparation of graphene stock solution for producing nanofibers, involves (1) mixing graphite powder and strong oxidizing mixture at mass ratio of 1:3 at room temperature for 20-30 minutes, stirring at 88 rpm and leaving the mixture still for 1 hour to obtain solution (A), (2) adding hydrogen peroxide to solution (A) and mixing well, the volume ratio of solution (A) and hydrogen peroxide is 7:5, and stirring for 30-60 minutes at rate of 110 rpm, leaving the mixture still for 2-3 hours to obtain solution (B), (3) adding high-potassium powder to solution (B), the mass ratio of solution (B) and potassium permanganate is 3:1, stirring for 25-55 minutes at 45-50 degrees C at rate of 135 rpm, ultrasonically vibrating for 30-40 minutes with frequency of 40-60 kHZ to obtain solution (C), (4) introducing chlorine gas into solution (C), and the volume ratio of solution (C) and chlorine gas is 10:13, reacting for 30-90 minutes and leaving still for 2 hours, ultrasonically vibrating for 60-90 minutes with ultrasonic frequency of 50-77 kHZ, centrifuging and washing lower layer with deionized water.