• 专利标题:   Multielement co-doped graphene quantum dots for e.g. supercapacitor electrode, comprise element doped by plasma treatment by placing graphene quantum dots doped with other element on moving stage that reciprocates, rotates, or vibrates in horizontal direction to uniformly plasma-treat quantum dots.
  • 专利号:   KR2338793-B1
  • 发明人:   SHIM W, SIM Y, KIM J Y, MUN J H, HO J C, KIM S J
  • 专利权人:   UNIV CHONNAM NAT IND FOUND, KOREA BASIC SCI INST
  • 国际专利分类:   C01B032/194, C23C016/00, H01G011/36
  • 专利详细信息:   KR2338793-B1 15 Dec 2021 C01B-032/194 202104 Pages: 172
  • 申请详细信息:   KR2338793-B1 KR073616 17 Jun 2020
  • 优先权号:   KR073616

▎ 摘  要

NOVELTY - A multielement co-doped graphene quantum dots comprise graphene quantum dots and two or more elements doped in the graphene quantum dots. The doped two or more elements include an element (E1) and an element (E2). The graphene quantum dots are doped with the element (E2) by plasma treatment in a gas atmosphere containing the element (E2) after the element (E1) is doped. The element (E2) is doped by plasma treatment by placing the graphene quantum dots doped with the element (E1) on a moving stage that reciprocates, rotates, or vibrates in the horizontal direction to uniformly plasma-treat the entire area of the graphene quantum dots. USE - Multielement co-doped graphene quantum dots used as electrocatalyst for water electrolysis and passivation film for supercapacitor electrode (all claimed). Can also be used for battery and fuel cell. ADVANTAGE - The multielement co-doped graphene quantum dots have excellent supercapacitor characteristics in the positive potential range induced by higher electronegativity by activation of electrochemical reaction due to the co-doping effect of multiple elements, and low overvoltage for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), thereby showing improved catalytic activity. The multielement co-doped graphene quantum dots form passivation film on the electrode in an aqueous system to prevent corrosion from aqueous solution, thereby suppressing deterioration of electrode performance and enabling long-term operation. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for manufacturing of multielement co-doped graphene quantum dots, which involves preparing graphene quantum dots, doping the graphene quantum dots with the element (E1), and doping the element (E2) to the graphene quantum dots doped with the element (E1).