• 专利标题:   Preparing silicon-loaded zeolite molecular sieve catalyst graphene packaging nickel involves adding zeolite molecular sieve and nickel nitrate and nickel acetate, adding nickel nitrate into flask as nickel source, and dissolving in ethanol to form solution A, citric acid, tartaric acid, malic acid.
  • 专利号:   CN114602546-A
  • 发明人:   WANG Z, LUO W, FU J, LV P, LI M
  • 专利权人:   GUANGZHOU ENERGY INST CONVERSION CHINESE
  • 国际专利分类:   B01J029/68, B01J029/76, B01J029/85, B01J037/08, B01J037/16, C10G003/00
  • 专利详细信息:   CN114602546-A 10 Jun 2022 B01J-029/85 202265 Chinese
  • 申请详细信息:   CN114602546-A CN11442460 08 Dec 2020
  • 优先权号:   CN11442460

▎ 摘  要

NOVELTY - Preparing silicon-loaded zeolite molecular sieve catalyst graphene packaging nickel involves adding any one of ZSM-22, ZSM-35 , and SAPO-11 zeolite molecular sieve and nickel nitrate and nickel acetate to metal load amount to 0.5-20 wt.%, adding any one of nickel nitrate into the flask as a nickel source and dissolving in ethanol to form solution A, citric acid, tartaric acid, malic acid, glucose, sucrose, fructose, D-sorbitol in the one kind of or more as a carbon source to dissolve in the deionized water B, the mol ratio range of the carbon source and the nickel source is 0.25-4.5, mixing solution A and the solution B and stirring at 40-105 degreesC, until liquid is completely volatilized, under the inert atmosphere, the solid mixture is further calcined for 0.5-10 hours at 150-800 degreesC, in the tubular furnace after roasting, the sample is cooled to room temperature in the inert atmosphere and then grinding and sieving, the obtained black powder is a target catalyst. USE - Method for preparing silicon-loaded zeolite molecular sieve catalyst graphene packaging nickel. ADVANTAGE - The method has good synergistic catalytic activity, and it improves the activity and stability of the nickel-type zeolite molecular sieve catalyst under the high temperature and high-pressure reaction system.