• 专利标题:   Preparing nickel-plated graphene to prepare graphene composite material, by mixing graphene and deionized water, adding DL-malic acid and nickel salt to graphene solution, ultrasonically processing, adding sodium borohydride and reducing.
  • 专利号:   CN106744902-A, CN106744902-B
  • 发明人:   XI X, GAN G
  • 专利权人:   YANCHENG INST TECHNOLOGY, YANCHENG INST TECHNOLOGY
  • 国际专利分类:   C01B032/194, C23C018/16, C23C018/18, C23C018/34
  • 专利详细信息:   CN106744902-A 31 May 2017 C01B-032/194 201751 Pages: 8 Chinese
  • 申请详细信息:   CN106744902-A CN10095498 22 Feb 2017
  • 优先权号:   CN10095498

▎ 摘  要

NOVELTY - Preparation method of nickel-plated graphene involves (a) mixing graphene and deionized water and then stirring to obtain graphene solution, adding DL-malic acid and nickel salt to the graphene solution and ultrasonically processing to obtain mixed solution (I), (b) adjusting pH of the mixed solution (I) to 10 using alkaline solution, adding sodium borohydride and carrying out reduction reaction to obtain mixed solution (II), and (c) adding nickel salt and sodium borohydride to mixed solution (II), ultrasonically processing, centrifugally washing and drying to obtain nickel-plated graphene. USE - Method is useful for preparing nickel-plated graphene, which is useful for preparing graphene composite material. ADVANTAGE - The method ensures rapid, economical and environmentally-friendly preparation of nickel-plated graphene without performing activation and sensitization process, and is suitable for large-scale production. DETAILED DESCRIPTION - Preparation method of nickel-plated graphene involves (a) mixing graphene and deionized water and then stirring to obtain graphene solution with a concentration of 0.1-2 mg/ml, adding DL-malic acid and nickel salt to the graphene solution and ultrasonically processing to obtain mixed solution (I), (b) adjusting pH of the mixed solution (I) to 10 using an alkaline solution, adding sodium borohydride and carrying out reduction reaction to obtain mixed solution (II), and (c) adding nickel salt and sodium borohydride to the mixed solution (II), ultrasonically processing, centrifugally washing and drying to obtain nickel-plated graphene.