• 专利标题:   Preparation of large-area graphene used for manufacturing microelectronic devices and biological sensors, involves cleaning silicon substrate, placing in deposition reaction chamber, introducing propane and silane gas, and annealing.
  • 专利号:   CN103183339-A
  • 发明人:   GUO H, LEI T, LIU J, ZHANG F, ZHANG Y
  • 专利权人:   UNIV XIDIAN
  • 国际专利分类:   C01B031/04
  • 专利详细信息:   CN103183339-A 03 Jul 2013 C01B-031/04 201402 Pages: 10 Chinese
  • 申请详细信息:   CN103183339-A CN10078984 12 Mar 2013
  • 优先权号:   CN10078984

▎ 摘  要

NOVELTY - A large-area graphene is prepared by cleaning silicon substrate, placing in chemical vapor deposition reaction chamber, heating, introducing propane and silane gas, performing hydrogen etching, heating, introducing silane gas, argon gas and chlorine gas, plating with copper film using physical vapor deposition method, annealing for 30 minutes and immersing in ferric chloride solution. USE - Method for preparing large-area graphene (claimed). ADVANTAGE - The graphene has smooth surface, good continuity and low porosity. DETAILED DESCRIPTION - A large-area graphene is prepared by cleaning 4-12 inches silicon substrate, placing in chemical vapor deposition reaction chamber at 7-10 mbar, heating at 1000-1500 degrees C, introducing propane gas with flow rate of 40 cm3/minute for 4-8 minutes, heating at 1150-1350 degrees C, introducing propane and silane gas for 36-60 minutes, performing hydrogen etching, heating at 850-900 degrees C, introducing silane gas with flow rate of 0.5-0.8 mL/minute for 12 minutes, heating at 800-1000 degrees C, introducing argon and chlorine gas for 4-7 minutes, plating with copper film using physical vapor deposition method, heating at 950-1150 degrees C, annealing for 30 minutes and immersing in ferric chloride solution.