• 专利标题:   Preparation of graphene oxide-polyurethane composite film used for e.g. separating oil and water involves mixing polyether polyol, polyisocyanate, foam stabilizer, triethylenediamine and other raw materials, standing, curing and washing.
  • 专利号:   CN104610728-A, CN104610728-B
  • 发明人:   LU J, CHEN D
  • 专利权人:   UNIV SOOCHOW
  • 国际专利分类:   C08G101/00, C08G018/48, C08G018/66, C08J003/24, C08J009/08, C08K003/04, C08K003/26, C08L075/08
  • 专利详细信息:   CN104610728-A 13 May 2015 C08L-075/08 201565 Pages: 9 Chinese
  • 申请详细信息:   CN104610728-A CN10046770 29 Jan 2015
  • 优先权号:   CN10046770

▎ 摘  要

NOVELTY - Preparation of graphene oxide-polyurethane composite film comprises mixing polyether polyol, polyisocyanate, foam stabilizer, triethylenediamine, stannous octoate, water, calcium carbonate and alkenyl graphite oxide for 1-5 minutes, standing for 5-10 minutes, curing for 1-2 hours, washing with polar solvent, soaking in hydrochloric acid/ethanol solution for 1-2 hours, removing calcium carbonate, drying, soaking in graphene oxide, adding crosslinking agent, removing air bubbles, reacting at 70-90 degrees C for 8-10 hours, washing and drying. USE - Method for preparing graphene oxide-polyurethane composite film used for separating oil and water, and transporting oil (all claimed). ADVANTAGE - The film is environment-friendly. The preparation method is convenient, suitable for industrial production, has easily obtainable raw materials and does not produce secondary pollution. DETAILED DESCRIPTION - Preparation of graphene oxide-polyurethane composite film comprises mixing polyether polyol, polyisocyanate, foam stabilizer, triethylenediamine, stannous octoate, water, calcium carbonate and alkenyl graphite oxide at ratio of 100-500:100-500:1-5:1-5:1-5:20-50:20-50:20-50 for 1-5 minutes, standing for 5-10 minutes, curing for 1-2 hours, washing with polar solvent, soaking in hydrochloric acid/ethanol solution for 1-2 hours, removing calcium carbonate, drying, soaking in graphene oxide, adding crosslinking agent, removing air bubbles, reacting at 70-90 degrees C for 8-10 hours, washing and drying. Volume ratio of crosslinking agent and graphene oxide is 1:10-20.