• 专利标题:   Electrolyte for preparing lithium-ion battery, comprises lithium salt, solvent such as carboxylic acid ester, fluoro carboxylic acid ester and fluoro ether, and additive A and additive B, where additive A is fluorophenyl difluorophosphate compound(s), and additive B is isocyanurate compound(s).
  • 专利号:   CN115832434-A
  • 发明人:   WANG J, CHEN J, LIN J, HE K, DU J
  • 专利权人:   ZHEJIANG YONGTAI TECHNOLOGY CO LTD, ZHEJIANG YONGTAI NEW ENERGY MATERIALS CO LTD
  • 国际专利分类:   H01M010/0525, H01M010/0567
  • 专利详细信息:   CN115832434-A 21 Mar 2023 H01M-010/0567 202328 Chinese
  • 申请详细信息:   CN115832434-A CN11288174 20 Oct 2022
  • 优先权号:   CN11288174

▎ 摘  要

NOVELTY - A lithium-ion battery electrolyte comprises a lithium salt, solvent, additive A and additive B. The additive A is selected from at least one fluorophenyl difluorophosphate compounds (I), and additive B is selected from at least one of the isocyanurate compounds (II). USE - Electrolyte is used in preparation of lithium-ion battery (claimed). ADVANTAGE - The additives of the electrolyte, contain fluorophenyl difluorophosphate and unsaturated isocyanurate, where the combined use of the two additives, protects the positive terminal, such that the battery impedance does not increase significantly, ensuring the high-temperature storage stability of the battery, without deteriorating the battery cycle performance. DETAILED DESCRIPTION - A lithium-ion battery electrolyte comprises a lithium salt, solvent, additive A and additive B. The additive A is selected from at least one fluorophenyl difluorophosphate compounds of formula (I), and additive B is selected from at least one of the isocyanurate compounds of formula (II). In formula (I), n =1-5. In formula (II), R1, R2, R3 = fluorine atom; 1-10C alkyl, 2-10C alkenyl, 2-10C alkynyl, 1-10C alkoxy, 1-10C fluoroalkyl, 1-10C fluoroalkoxy, 2-10C cyanoalkyl, 2-10C isocyanatoalkyl, provided at least one of R1, R2 and R3 contains an unsaturated bond. An INDEPENDENT CLAIM is included for lithium-ion battery which comprises anode sheet, cathode sheet, diaphragm and the electrolyte. The anode sheet comprises an anode current collector, anode active material, a conductive agent and a binder. The cathode sheet comprises a cathode current collector, cathode active material, a conductive agent and a binder. Further, the anode active material is lithium nickel cobalt compound (LiNi1-x-y-z CoxMnyAlzO2, where x=0-1, y=0-1, z= 0-1 and x+y+z= 0-1. The cathode active material is artificial graphite, natural graphite, composite graphite, graphene, intermediate of phase microspheres, nano-silicon, silicon-carbon composite materials and/or silicon oxide/carbon composite materials.