• 专利标题:   Composite used in electrode assembly and gas separation system, comprises vertically aligned carbon nanotubes, and electroactive species capable of bonding with target gas and releasing target gas when in first and second oxidation states.
  • 专利号:   WO2022104000-A1
  • 发明人:   VOSKIAN S, ROGERS C
  • 专利权人:   VERDOX INC
  • 国际专利分类:   B01D053/32, B64D037/32, C25B001/00
  • 专利详细信息:   WO2022104000-A1 19 May 2022 B01D-053/32 202252 Pages: 40 English
  • 申请详细信息:   WO2022104000-A1 WOUS059048 12 Nov 2021
  • 优先权号:   US113321P

▎ 摘  要

NOVELTY - Composite comprises vertically aligned carbon nanotubes, and an electroactive species disposed on the vertically aligned nanotube. The electroactive is capable of bonding with a target gas when in a first oxidation state, and releasing the gas when the species is in a second oxidation state. The composite further comprises: carbon fibers, graphene, reduced graphene oxide, carbon black, Ketjen black, or structured carbon black; and a polymer binder. USE - The composite is useful: in an electrode assembly, an electrochemical cell, and a gas separation system for separating a target gas e.g. carbon dioxide or sulfur dioxide from a gas mixture; and capturing a target gas using an electroswing adsorption cell. ADVANTAGE - The composite enables a higher capture rate than when using a thicker or less porous material. The thicker layer of vertically aligned carbon nanotubes (VACNTs) can form a structured or patterned electrode, providing a shorter diffusion pathway for the target species and enabling a high capture rate when other materials are used. Additionally, coating the electroactive species on the carbon nanotubes can provide improved cycle life. Thus, a significant improvement is provided by the composite of the present disclosure. DETAILED DESCRIPTION - INDEPENDENT CLAIMs are also included for: (1) an electrode assembly comprising a porous separator; (2) an electrochemical cell; (3) a gas separation system comprising a electrochemical cells in fluid communication with a gas inlet and a gas outlet; and (4) making the composite. DESCRIPTION OF DRAWING(S) - The drawing shows a schematic view of the graph of cell voltage and current (amperes, A) versus time (seconds, s) for the sealed cell.