• 专利标题:   Catalyst used in gas-phase plug flow reactor for carbonylation of alcohol e.g. lower alcohol and carbonylation of ester e.g. methyl acetate, comprises support and metal oxide dispersed on surface of support.
  • 专利号:   WO2021118761-A1, US2023001385-A1
  • 发明人:   CHRISTOPHER P, QI J
  • 专利权人:   UNIV CALIFORNIA, UNIV CALIFORNIA
  • 国际专利分类:   B01J023/06, B01J023/20, B01J023/36, B01J023/00, B01J023/40, B01J035/10, C07C051/12
  • 专利详细信息:   WO2021118761-A1 17 Jun 2021 B01J-023/06 202155 Pages: 87 English
  • 申请详细信息:   WO2021118761-A1 WOUS060725 16 Nov 2020
  • 优先权号:   US935182P, US17776933

▎ 摘  要

NOVELTY - A catalyst comprises a support and a metal oxide dispersed on a surface of the support. USE - Catalyst is used in gas-phase plug flow reactor for carbonylation of alcohol e.g. 1-20C alcohol, 1-10C alcohol, or 1-5C alcohol, and ester e.g. methyl acetate, methyl propionate, and/or methyl butyrate (all claimed). ADVANTAGE - The catalyst has improved selectivity and stability, and comprises support which is typically chemically inert and has high surface area. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) gas-phase plug flow reactor, which has a reaction chamber, a catalyst bed provided inside the reaction chamber and the catalyst packed inside, a gas inlet, and a gas outlet. The gas inlet and gas outlet are in fluid communication with the reaction chamber; (2) carbonylation of alcohol, which involves exposing a mixture of one or more alcohols and carbon monoxide in a gas phase to the catalyst; and (3) carbonylation of ester, which involves exposing a mixture of one or more esters and carbon monoxide in a gas phase to the catalyst.