• 专利标题:   Preparing modified sulfur-containing graphene material comprises e.g. mixing graphene oxide and sulfur-containing small molecules in solvent A under nitrogen atmosphere, centrifuging and then washing to obtain sulfurized graphene oxide.
  • 专利号:   CN107325590-A, CN107325590-B
  • 发明人:   XUE L, WANG X, TAN D, ZHENG Y
  • 专利权人:   UNIV WUHAN, UNIV WUHAN
  • 国际专利分类:   C08K003/04, C08K009/02, C08K009/06, C08L007/00, C08L083/04, C09C001/46, C09C003/08, C09C003/12, H01B003/28
  • 专利详细信息:   CN107325590-A 07 Nov 2017 C09C-001/46 201802 Pages: 7 Chinese
  • 申请详细信息:   CN107325590-A CN10539142 04 Jul 2017
  • 优先权号:   CN10539142

▎ 摘  要

NOVELTY - Preparing modified sulfur-containing graphene material comprises e.g. mixing 10-100 pts. wt. graphene oxide and 5-90 pts. wt. sulfur-containing small molecules in solvent A under nitrogen atmosphere, centrifuging, washing to obtain sulfurized graphene oxide, adding modified sulfurized graphene oxide into aqueous solution, adjusting pH to 11, then adding hydrazine hydrate, refluxing, centrifuging reaction solution, washing, drying to obtain modified sulfur-containing graphene, where sulfur-containing small molecule is Lawson's reagent, phosphorus pentasulfide or ammonium thiocyanate. USE - The material is useful in the field of information transmission (claimed). ADVANTAGE - The material has flame retardant, increases wear resistance, and enhances mechanical property of cable shield. DETAILED DESCRIPTION - Preparing modified sulfur-containing graphene material comprises mixing 10-100 pts. wt. graphene oxide and 5-90 pts. wt. sulfur-containing small molecules in solvent A under nitrogen atmosphere for 6-24 hours, centrifuging, washing to obtain sulfurized graphene oxide, adding modified sulfurized graphene oxide into aqueous solution, adjusting pH to 11, then adding hydrazine hydrate, refluxing at 98 degrees C for 12-24 hours, centrifuging reaction solution, washing, drying to obtain modified sulfur-containing graphene, where sulfur-containing small molecule is Lawson's reagent, phosphorus pentasulfide, ammonium thiocyanate, mercaptoethylamine, p-aminothiophenol, polysulfide silane coupling agent, mercaptosilane coupling agent or thiocarboxylate silane coupling agent, and solvent A is tetrahydrofuran, acetonitrile or N-methylpyrrolidone. INDEPENDENT CLAIMS is also included for: (1) modified sulfur-containing graphene material is obtained by above mentioned method; and (2) modified sulfur-containing graphene doped cable shielding layer material comprises 100 pts. wt. rubber, 1-5 pts. wt. modified sulfur-containing graphene, 10-20 pts. wt. white carbon and 0.5-1 pts. wt. antioxidant, where rubber is natural rubber, isoprene rubber, styrene-butadiene rubber, nitrile rubber and silicone rubber.