• 专利标题:   Method for preparing catalyst that is utilized in direct methanol fuel cell, involves preparing functionalized phthalocyanine tetrasulfonate iron based complex-graphene composite followed by using chloroplatinic acid and processing.
  • 专利号:   CN108615898-A
  • 发明人:   FAN Y, ZHONG J, XIANG S, TANG H
  • 专利权人:   UNIV GUANGXI NORMAL
  • 国际专利分类:   H01M004/88, H01M004/92, B82Y030/00
  • 专利详细信息:   CN108615898-A 02 Oct 2018 H01M-004/88 201872 Pages: 7 Chinese
  • 申请详细信息:   CN108615898-A CN10334947 15 Apr 2018
  • 优先权号:   CN10334947

▎ 摘  要

NOVELTY - A catalyst preparation method involves adding 10 mg graphene and 8-50 mg phthalocyanine tetrasulfonate iron based complex to container containing triple distilled water, ultrasonically dispersing at room temperature for 6 hours, centrifuging obtained product, vacuum drying to obtain functionalized phthalocyanine tetrasulfonate iron based complex-graphene composite, placing obtained composite (20 mg) in quartz tube furnace, heat treating at 300-1000 degrees C for 3 hours in presence of argon to obtain iron-sulfur-nitrogen co-doped graphene composite material, adding obtained composite material (10 mg) and 19.3 mM chloroplatinic acid to 20 ml ethylene glycol, ultrasonically processing for 2 hours, reacting at 80-180 degrees C for 24 hours, centrifuging, washing and vacuum drying. USE - Method for preparing catalyst that is utilized in direct methanol fuel cell (claimed). ADVANTAGE - The method enables preparing catalyst with improved electrocatalytic activity for methanol oxidation and oxygen reduction reaction, excellent electrochemical stability and ability to resist carbon monoxide poisoning in a simple manner under mild and controlled conditions by enhancing synergistic coupling effect between catalytic nanoparticles and iron-sulfur-nitrogen co-doped graphene carrier. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for a catalyst prepared by the method.