• 专利标题:   Layered nanocomposite material used as sodium ion battery cathode active material, is prepared by dissolving e.g. sodium carbonate in deionized water, reacting, adding graphene oxide, stirring, drying, grinding and calcining.
  • 专利号:   CN105375008-A, CN105375008-B
  • 发明人:   MAI L, XU Y, AN Q, WEI J, CHENG J
  • 专利权人:   UNIV WUHAN TECHNOLOGY
  • 国际专利分类:   B82Y030/00, B82Y040/00, H01M010/054, H01M004/36, H01M004/48, H01M004/58
  • 专利详细信息:   CN105375008-A 02 Mar 2016 H01M-004/36 201649 Pages: 13 English
  • 申请详细信息:   CN105375008-A CN10772387 13 Nov 2015
  • 优先权号:   CN10772387

▎ 摘  要

NOVELTY - A layered reduced graphene oxide-coated sodium-vanadium phosphate nanocomposite material is prepared by dissolving 0.75-3 mmol sodium carbonate, 1-4 mmol vanadyl acetylacetonate and 1.5-6 mmol ammonium dihydrogen phosphate in deionized water, ultrasonically processing resultant solution, stirring, adding resultant light blue precursor to a reactor, hydrothermally reacting, cooling to room temperature, adding 10-30 mg graphene oxide to obtained green jelly-like gel, stirring, drying obtained homogeneous dispersion, grinding dried product and calcining. USE - Layered reduced graphene oxide-coated sodium-vanadium phosphate nanocomposite material is used as sodium ion battery cathode active material (claimed). ADVANTAGE - The layered reduced graphene oxide-coated sodium-vanadium phosphate nanocomposite material has excellent durability and cycle stability, and high rate characteristics and magnification, and is prepared by simple process. DETAILED DESCRIPTION - A layered reduced graphene oxide-coated sodium-vanadium phosphate (Na3V2(PO4)3) nanocomposite material comprises a laminar structure comprising sodium-vanadium phosphate nanoparticles and a reduced graphene oxide nanosheet layer overlapped the laminar structure. The layered reduced graphene oxide-coated sodium-vanadium phosphate nanocomposite material is prepared by dissolving 0.75-3 mmol sodium carbonate, 1-4 mmol vanadyl acetylacetonate and 1.5-6 mmol ammonium dihydrogen phosphate in deionized water, in stoichiometric ratio of 1.5:2:3, ultrasonically processing resultant solution, stirring, adding resultant light blue precursor to a reactor, hydrothermally reacting, cooling to room temperature, adding 10-30 mg graphene oxide to obtained green jelly-like gel, stirring, drying obtained homogeneous dispersion, grinding dried product and calcining. An INDEPENDENT CLAIM is included for preparation of layered reduced graphene oxide-coated sodium-vanadium phosphate nanocomposite material.