• 专利标题:   Method for electrochemically preparing graphene/manganese dioxide composite material used as electrode, involves depositing manganese dioxide on graphene surface, and controlling particle size and distribution density of manganese dioxide.
  • 专利号:   CN102568847-A, CN102568847-B
  • 发明人:   LI Z, GU Z, YAN T, NIU Y, ZHOU L
  • 专利权人:   UNIV JIANGNAN
  • 国际专利分类:   H01G009/042
  • 专利详细信息:   CN102568847-A 11 Jul 2012 H01G-009/042 201335 Pages: 8 Chinese
  • 申请详细信息:   CN102568847-A CN10425512 16 Dec 2011
  • 优先权号:   CN10425512

▎ 摘  要

NOVELTY - A graphene/manganese dioxide composite material preparing method involves reducing a graphene oxide into graphene. The graphene is uniformly fixed on an electrode surface. Thickness of a graphene coating layer is controlled. Manganese acetate and sodium sulfate are taken as a manganese precursor and a supporting electrolyte. Acidity of the electrolyte is adjusted and controlled potential electrolysis is performed. Manganese dioxide is electrically deposited on a graphene surface. Particle size and distribution density of the manganese dioxide are controlled to prepare the composite material. USE - Method for electrochemically preparing a graphene/manganese dioxide composite material that is utilized as an electrode or a supercapacitor assembly. ADVANTAGE - The method enables improving the capacity and cyclic charging and discharging characteristics of the supercapacitor assembly. DETAILED DESCRIPTION - A graphene/manganese dioxide composite material preparing method involves taking sodium carbonate as a supporting electrolyte and reducing a graphene oxide into graphene by a controlled potential electrolysis method. The graphene is uniformly fixed on a surface of an electrode. Thickness of a graphene coating layer is precisely controlled according to the concentration of the graphene oxide, potential, temperature and time during electro-deposition. Manganese acetate and sodium sulfate are taken as a manganese precursor and a supporting electrolyte. Acidity of the electrolyte is adjusted by sulfuric acid and controlled potential electrolysis is performed. Manganese dioxide is electrically deposited on the graphene surface. Particle size and the distribution density of the manganese dioxide are precisely controlled to prepare the graphene/manganese dioxide composite material. An INDEPENDENT CLAIM is also included for a method for using a graphite/manganese dioxide composite material, which involves utilizing acetonitrile or ethanol solution as an ionic liquid electrolyte of a supercapacitor assembly, where the concentration of the ionic liquid is 0.1-10 mole/l. DESCRIPTION OF DRAWING(S) - The drawing shows a flow diagram illustrating a method for electrochemically preparing a graphene/manganese dioxide composite material. '(Drawing includes non-English language text)'