• 专利标题:   Toughening modification of ultra-low temperature epoxy resin involves preparing graphene oxide/nano cellulose solution, adding e.g. diethylenetriamine, epoxy resin and curing agent, mixing and casting in mold and vacuum defoaming.
  • 专利号:   CN112409754-A
  • 发明人:   JIAO W, YAN M, WANG R, HE X
  • 专利权人:   SHENZHEN XICHUANG ADVANCED MATERIAL INST
  • 国际专利分类:   C08G083/00, C08L063/00, C08L087/00
  • 专利详细信息:   CN112409754-A 26 Feb 2021 C08L-063/00 202128 Pages: 9 Chinese
  • 申请详细信息:   CN112409754-A CN11086777 12 Oct 2020
  • 优先权号:   CN11086777

▎ 摘  要

NOVELTY - Toughening modification of ultra-low temperature epoxy resin involves dissolving 50-150 mg graphene oxide and 100 mg nano cellulose in 100 ml distilled water to obtain graphene oxide/nano cellulose solution, adjusting pH to 4-6, adding 20-60 g diethylenetriamine, 0.3-0.9 g 1-ethyl-(3-dimethylamino-propyl)carbodiimide hydrochloride and 0.18-0.54 g N-hydroxysuccinimide into the prepared solution, stirring for 1-3 days at room temperature to obtain graphene oxide-nano cellulose nano composite material, uniformly dispersing the composite material in a solvent, stirring while adding epoxy resin, evaporating and recycling the solvent until the evaporation of solvent is complete, adding curing agent, mixing and casting in a mold, vacuum defoaming and curing. The addition amount of graphene grafted nano-cellulose is 0.1-0.5 wt.% of graphene oxide-nano cellulose and epoxy resin. USE - Toughening modification of ultra-low temperature epoxy resin. ADVANTAGE - The process produces epoxy resin having crack pinning phenomenon with effective inhibition of germination and expansion of crack, and enhanced low-temperature toughness.