• 专利标题:   Producing zirconium dioxide nanocomposite with reduced graphene oxide, comprises e.g. separately dispersing graphene oxide and acetylacetonate zirconium(IV) in water and ethylene glycol, mixing, instilling hydrochloric acid, and heating.
  • 专利号:   PL409672-A1, PL225765-B1
  • 发明人:   MIJOWSKA E, URBAS K
  • 专利权人:   UNIV ZACHODNIOPOMORSKI TECHNOLOGICZNY, UNIV ZACHODNIOPOMORSKI TECHNOLOGICZNY, PODOLSKI JACEK NIEPUBLICZNY ZAKLD OPIEKI ZDROWOTNEJ MEDITEST
  • 国际专利分类:   C01B031/02, C01G025/02, B82Y040/00, C01G001/02, C08K003/04, C08K003/22
  • 专利详细信息:   PL409672-A1 11 Apr 2016 C01G-025/02 201641 Pages: 1
  • 申请详细信息:   PL409672-A1 PL409672 03 Oct 2014
  • 优先权号:   PL409672

▎ 摘  要

NOVELTY - Producing zirconium dioxide nanocomposite with reduced graphene oxide, comprises: dispersing graphene oxide in a mixture of water and ethylene glycol using an ultrasonic probe; dispersing acetylacetonate zirconium(IV) in water and ethylene glycol using ultrasound; mixing the obtained dispersions and instilling a solution of hydrochloric acid; setting the pH of the mixture at 3-7; then placing the mixture in an autoclave, heating to 270-300 degrees C, and maintaining this temperature for 6-12 hours; cooling and subjecting to filtration; and repeatedly washing with water and ethanol and drying. USE - The method is useful for producing zirconium dioxide nanocomposite with reduced graphene oxide. DETAILED DESCRIPTION - Producing zirconium dioxide nanocomposite with reduced graphene oxide, comprises: dispersing graphene oxide in a mixture of water and ethylene glycol using an ultrasonic probe; dispersing acetylacetonate zirconium(IV) in water and ethylene glycol using ultrasound; mixing the obtained dispersions and instilling a solution of hydrochloric acid; setting the pH of the mixture at 3-7; then placing the mixture in an autoclave, heating to 270-300 degrees C, and maintaining this temperature for 6-12 hours; cooling the mixture and subjecting to filtration on a polycarbonate membrane with a pore size of 0.2 mu m; and repeatedly washing the resulting material with water and ethanol and drying in vacuo at 100 degrees C. The weight ratio of graphene oxide to acetoacetate zirconium (IV) is 1:1 to 2:1. The weight ratio of graphene oxide to ethylene glycol is 1:743. The weight ratio of acetoacetate zirconium (IV) to ethylene glycol is 1:743.