• 专利标题:   Manufacturing copper oxide-zinc oxide/reduced graphene oxide composite, comprises oxidizing graphite to obtain graphene oxide, mixing graphene oxide with ethylene glycol, ultrasonically vibrating, adding reducing agent, and reducing.
  • 专利号:   KR1470927-B1
  • 发明人:   NAM S C, SONG H S, YOON Y, JEONG S K, PARK S Y, PARK M G, AHN W, JEONG M H, CROISET E, CHEN Z
  • 专利权人:   KOREA INST ENERGY RES
  • 国际专利分类:   B01J019/10, B01J019/18, C01B031/02, C01G003/02
  • 专利详细信息:   KR1470927-B1 09 Dec 2014 C01G-003/02 201503 Pages: 13
  • 申请详细信息:   KR1470927-B1 KR110094 13 Sep 2013
  • 优先权号:   KR110094

▎ 摘  要

NOVELTY - Manufacturing copper oxide-zinc oxide/reduced graphene oxide composite, comprises oxidizing graphite with oxidizing agent in presence of acid, and peeling to obtain graphene oxide; mixing the graphene oxide with ethylene glycol by ultrasonically vibrating to obtain primary dispersion; coarsely mixing primary dispersion with sodium hydroxide aqueous solution, and ultrasonically vibrating to obtain second dispersion; coarsely mixing secondary dispersion with zinc acetate and copper acetate aqueous solution, and stirring; adding reducing agent into coarse mixture, and carrying out reduction. USE - The method is useful for manufacturing copper oxide-zinc oxide/reduced graphene oxide composite. ADVANTAGE - The method prevents aggregation phenomenon of the zinc oxide particles, adjusts copper oxide-zinc oxide ratio so as to achieve better hydrogen sulfide adsorption rate, and thus maximizes the hydrogen sulfide adsorption rate of the compound. DETAILED DESCRIPTION - Manufacturing copper oxide-zinc oxide/reduced graphene oxide composite, comprises oxidizing graphite with an oxidizing agent in presence of an acid, and peeling to obtain graphene oxide; mixing the graphene oxide with ethylene glycol by ultrasonically vibrating to obtain primary dispersion; coarsely mixing the primary dispersion with sodium hydroxide aqueous solution, and ultrasonically vibrating to obtain second dispersion; coarsely mixing the secondary dispersion with zinc acetate and copper acetate aqueous solution, and stirring at a fixed rate with a magnetic stirrer; adding reducing agent into the coarse mixture, and carrying out reduction by heat treatment; cooling the reduced mixture, then washing with distilled water, and freeze drying in a vacuum dryer.