• 专利标题:   Preparation of high conductivity type graphene-resin composite material, involves adding natural flake graphite and anhydrous ferric chloride into closed vacuum tube, and heating to obtain ferric chloride intercalated graphite.
  • 专利号:   CN105820514-A
  • 发明人:   BAI Y, DING R, GUO X, LI X, LIANG H, LIANG Z, LV Y, NI Z, SHAO Y, WU Y, YAN C, YU Y, ZHAO H
  • 专利权人:   CHINA WEAPON IND NEW TECHNOLOGY PROMOTIO, TAIZHOU SUNANO NEW ENERGY CO LTD, INNER MONGOLIA INST GRAPHENE MATERIALS
  • 国际专利分类:   C08K003/04, C08K007/00, C08K009/02, C08L063/02
  • 专利详细信息:   CN105820514-A 03 Aug 2016 C08L-063/02 201679 Pages: 6 Chinese
  • 申请详细信息:   CN105820514-A CN10218633 08 Apr 2016
  • 优先权号:   CN10218633

▎ 摘  要

NOVELTY - The preparation method of high conductivity type graphene-resin composite material involves (i) adding natural flake graphite and anhydrous ferric chloride into a vacuum tube, heating to obtain ferric chloride intercalated graphite, (ii) placing ferric chloride intercalated graphite and hydrogen peroxide in beaker to obtain graded graphite, (iii) mixing bisphenol A type E-51 epoxy resin and polyether amine D230 resin curing agent to obtain mixture (i), (iv) adding graded graphene to the mixture (i), stirring and mixing to obtain mixture (ii), (v) curing the mixture (ii), and cooling. USE - Preparation of high conductivity type graphene-resin composite material (claimed). ADVANTAGE - The method enables the preparation of graphene-resin composite material having high electrical conductivity. DETAILED DESCRIPTION - The preparation method of high conductivity type graphene-resin composite material involves (i) adding natural flake graphite and anhydrous ferric chloride into a closed vacuum tube, heating at 320-360 degrees C for 12-48 hours to obtain ferric chloride intercalated graphite, (ii) placing ferric chloride intercalated graphite and an appropriate amount of hydrogen peroxide in a beaker at room temperature for 2 to 6 hours, stripping the intercalated graphite to obtain graded graphite, (iii) mixing bisphenol A type E-51 epoxy resin and polyether amine D230 resin curing agent in a ratio of 3:1 to obtain a mixture (i), (iv) adding graded graphene to the mixture (i), stirring and mixing at 12-18 degrees C for 2-10 hours to obtain mixture (ii), (v) curing the mixture (ii) at 80-120 degrees C for 2-6 hours, and cooling to room temperature. The content of graded graphene in mixture (ii) is 1-5%.