• 专利标题:   Graphene aerogel/metal lithium composite anode material comprises graphene aerogel having vertical pore channels connected up and down as framework, and lithium metal filled inside vertical pore channels.
  • 专利号:   CN111048750-A
  • 发明人:   XIE M, ZHOU J, WU F, XIA X, JIANG W, WEI G
  • 专利权人:   BEIJING INST TECHNOLOGY, GUANGZHOU GREAT POWER ENERGY TECHNOLOG, GRINM ENG TECHNOLOGY RES INST CO LTD
  • 国际专利分类:   H01M010/052, H01M004/36, H01M004/38, H01M004/62, H01M004/66
  • 专利详细信息:   CN111048750-A 21 Apr 2020 H01M-004/36 202039 Pages: 13 Chinese
  • 申请详细信息:   CN111048750-A CN11102772 12 Nov 2019
  • 优先权号:   CN11102772

▎ 摘  要

NOVELTY - Graphene aerogel/metallic lithium composite anode material comprises a graphene aerogel having vertical pore channels connected up and down as a framework, and lithium metal filled inside the vertical pore channels of the graphene aerogel, where the pore size of the vertical pore channel of the graphene aerogel is 10-50 mu m, and the mass fraction of metallic lithium in the composite anode material is 90% or more. USE - The graphene aerogel/metal lithium composite negative electrode material is used as a negative electrode of a lithium metal battery using an ether electrolyte (claimed). ADVANTAGE - The three-dimensional porous framework effectively limits the volume expansion during the electrochemical cycle, and the high specific surface area of the three-dimensional porous framework effectively reduces the actual current density and inhibits the growth of lithium dendrites. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing the graphene aerogel/metallic lithium composite anode material comprising adding a reducing agent to an aqueous solution of graphene oxide, carrying out hydrothermal reaction at 50-80 degrees C for 3-5 hours, and placing in a hydroalcoholic solution for dialysis to remove the remaining reducing agent, and transferring to a copper plate placed under liquid nitrogen for vertical freezing until the upper surface is frozen, transferring to a freeze dryer for freeze-drying, and calcining at 300-600 degrees C for 2-4 hours to obtain a vertical pore channel graphene aerogel, depositing metallic lithium in the vertical pore channels of the graphene aerogel by electrodeposition to obtain the product.