• 专利标题:   Bifunctional heterogeneous palladium-MIL101-sulfonated graphene oxide composite material for beta-alkoxyalcohol catalytic synthesis, is prepared by stirring e.g. sulfonated graphene oxide, terephthalic acid and chromium nitrate nonahydrate.
  • 专利号:   CN111151301-A
  • 发明人:   ZHANG Y, TANG H, LI X, ZHOU M, WU Q, LIU D
  • 专利权人:   UNIV LIAONING
  • 国际专利分类:   B01J031/22, B01J037/02, B01J037/10, B01J037/16, C07C041/03, C07C043/178, C07D301/19, C07D303/04
  • 专利详细信息:   CN111151301-A 15 May 2020 B01J-031/22 202050 Pages: 7 Chinese
  • 申请详细信息:   CN111151301-A CN10029856 13 Jan 2020
  • 优先权号:   CN10029856

▎ 摘  要

NOVELTY - Bifunctional heterogeneous palladium (Pd)-MIL101-sulfonated graphene oxide (SGO) composite material is prepared by adding SGO, terephthalic acid, chromium nitrate nonahydrate, concentrated hydrochloric acid and water into a container, stirring, ultrasonically treating until the suspension is uniformly dispersed, introducing the suspension into a reaction kettle, sealing the reaction kettle, putting in an oven, keeping at 493 K for 8 hours, cooling to room temperature, standing for 1 day, washing with water, ethanol and dichloromethane, filtering and drying to obtain MIL-101-SGO solid, dissolving palladium chloride with solvent, adding sodium salt, reacting to obtain sodium tetrachloropalladate (II) solution, slowly dripping into the MIL-101-SGO solid to obtain intermediate Pd2+-MIL-101-SGO, and carrying out reduction reaction with a reducing agent. USE - The bifunctional heterogeneous Pd-MIL101-SGO composite material is used for catalytic one-pot tandem synthesis of beta -alkoxyalcohol using styrene (claimed). DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for use of the composite material for catalytic one-pot tandem synthesis of beta -alkoxyalcohol using styrene.