• 专利标题:   Preparing erbium-doped zinc oxide nano-sheet based on uranium photo-catalytic reduction useful in electrode materials, comprises e.g. reacting zinc nitrate hexahydrate, hexamethylene tetramine, graphene oxide solution and erbium chloride hexahydrate mixed solution, washing, drying and annealing.
  • 专利号:   CN115106077-A, CN115106077-B
  • 发明人:   LEI J, YANG F, LI R, SUN N, LIU H, GONG X, CHEN T, HE R, ZHU W
  • 专利权人:   UNIV SOUTHWEST SCI TECHNOLOGY
  • 国际专利分类:   B01J023/10, C02F001/30, C02F001/70
  • 专利详细信息:   CN115106077-A 27 Sep 2022 B01J-023/10 202302 Chinese
  • 申请详细信息:   CN115106077-A CN10725070 24 Jun 2022
  • 优先权号:   CN10725070

▎ 摘  要

NOVELTY - Preparing erbium-doped zinc oxide nano-sheet based on uranium photo-catalytic reduction comprises (i) dispersing the zinc nitrate hexahydrate and hexamethylene tetramine in water, stirring and adding the monolayer graphene oxide solution and erbium chloride hexahydrate to obtain a mixed solution; (ii) adding the mixed solution into the reaction kettle, reacting at 140-160℃, washing the obtained sample with ethanol, centrifuging and drying; and (iii) annealing the dried sample at 700-900℃. USE - The method is useful for preparing erbium-doped zinc oxide nano-sheet based on uranium photo-catalytic reduction is useful for irradiating the photocatalyst with 50-500 kGy 60Co γ-rays for photocatalytic testing and in electrode materials and radioactive wastewater treatment (all claimed) and for photocatalytic treatment of uranium-containing wastewater. ADVANTAGE - The method prepares erbium-doped zinc oxide nano-sheet based on uranium photo-catalytic reduction can remove uranium in a short time and has good repeatability and anti-interference. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: Application of erbium-doped zinc oxide nano-sheet based on uranium photo-catalytic reduction in electrode materials, comprising mixing 3 mg erbium-doped zinc oxide nanosheets, 9 mg carbon black, 30 µl (0.5 wt.%) (Sulfonated tetrafluoroethylene based fluoropolymer-copolymer) solution, and 4 ml ethanol, treating ultrasonically for 1 hour to obtain the carbon-based catalyst ink, brushing the carbon-based catalyst ink evenly on a 1×2 cm carbon paper, drying to obtain a working electrode, using platinum sheet as the counter electrode and silver/silver chloride as the reference electrode and carrying out the electrochemical performance test on the electrochemical workstation; andNafion Application of erbium-doped zinc oxide nano-sheet based on uranium photo-catalytic reduction in radioactive wastewater treatment, comprising taking erbium-doped zinc oxide nanosheets, adding them into uranium-containing radioactive wastewater, stirring uranium-containing radioactive wastewater for 30 minutes in dark conditions and carrying out photocatalytic reaction under xenon lamp simulated sunlight conditions to realize photocatalytic reduction of hexavalent uranium in uranium-containing radioactive wastewater.