• 专利标题:   Preparation of modified graphene oxide adsorbing material by dispersing graphene oxide in N,N-dimethylformamide, adding diphenyl methane diisocyanate, cooling with anhydrous N,N-dimethylformamide, drying, ball milling, and freezing.
  • 专利号:   CN107497404-A
  • 发明人:   YANG Y, YU Y, YANG N, HUANG B, LIAO Y
  • 专利权人:   UNIV CENT SOUTH FORESTRY TECHNOLOGY
  • 国际专利分类:   B01J020/22, B01J020/30, C02F001/28, C02F101/20
  • 专利详细信息:   CN107497404-A 22 Dec 2017 B01J-020/22 201812 Pages: 6 Chinese
  • 申请详细信息:   CN107497404-A CN10969875 18 Oct 2017
  • 优先权号:   CN10969875

▎ 摘  要

NOVELTY - Preparation of modified graphene oxide adsorbing material comprises dispersing 100 mg graphene oxide in anhydrous N,N-dimethylformamide, adding 1-3 mL diphenyl methane diisocyanate, stirring at 40-80 degrees C, reacting for 1-4 hours, cooling with anhydrous N,N-dimethylformamide, washing for 3 times, centrifugally separating, and vacuum drying to obtain diphenyl methane diisocyanate functionalized graphene oxide; and mixing diphenyl methane diisocyanate functionalized graphene oxide and EDTA, ball milling, freezing and drying material. USE - Method for preparing modified graphene oxide adsorbing material (claimed). ADVANTAGE - The material has excellent adsorption performance for heavy metal ions in wastewater. DETAILED DESCRIPTION - Preparation of modified graphene oxide adsorbing material comprises dispersing 100 mg graphene oxide in anhydrous N,N-dimethylformamide, adding 1-3 mL diphenyl methane diisocyanate, stirring at 40-80 degrees C, reacting for 1-4 hours, cooling with anhydrous N,N-dimethylformamide, washing for 3 times, centrifugally separating, and vacuum drying to obtain diphenyl methane diisocyanate functionalized graphene oxide; and mixing diphenyl methane diisocyanate functionalized graphene oxide and EDTA at weight ratio of 1:20-40, mixing uniformly, putting in ball mill, controlling ratio of grinding media to material at 1.5-3:1, milling at 60-100 rad/minute for 1-6 minutes, freezing and drying to obtain acid/diphenyl methane diisocyanate/graphene oxide composite material.