• 专利标题:   Preparing nitrogen-doped graphene by adding graphite powder, sodium nitrate, concentrated sulfuric acid and potassium permanganate, heating, adding hydrogen peroxide, washing precipitate, dialyzing, adding urea, freeze-drying and heating.
  • 专利号:   CN110790267-A
  • 发明人:   SHENG Z, WEI K, YIN J, ZHONG H, ZHANG L
  • 专利权人:   HUAIYIN NORMAL UNIVERSITY
  • 国际专利分类:   C01B032/192
  • 专利详细信息:   CN110790267-A 14 Feb 2020 C01B-032/192 202021 Pages: 16 Chinese
  • 申请详细信息:   CN110790267-A CN11066884 04 Nov 2019
  • 优先权号:   CN11066884

▎ 摘  要

NOVELTY - Method for preparing nitrogen-doped graphene involves adding graphite powder and sodium nitrate to concentrated sulfuric acid to form a first reaction system, adding potassium permanganate under stirring, heating at first predetermined temperature, continuing to stir for first predetermined time to form a second reaction system, adding deionized water, heating at a second predetermined temperature, continuing to stir for a second predetermined time to obtain a third reaction system, diluting with deionized water and adding hydrogen peroxide until no air bubble is formed to obtain a fourth reaction system, leaving still until delamination occurs, removing supernatant, washing lower precipitate, placing in a dialysis bag to dialyze to neutrality, drying dialysis product to obtain graphite oxide, dispersing in deionized water, adding urea or ammonium salt, mixing, freeze-drying, heating at 700-1000 degrees C, maintaining for 15-25 minutes, and cooling to room temperature to obtain the product. USE - The method is useful for preparing nitrogen-doped graphene. ADVANTAGE - The method is high in efficiency and environmentally-friendly.