• 专利标题:   Modified electrode useful for lithium-ion battery used in consumer electronics, intelligent robot and electric vehicle, comprises electrode and modified layer containing composite oxide of lithium and metal, which is aluminum, titanium, zirconium, tungsten, tantalum and/or hafnium.
  • 专利号:   CN114649531-A
  • 发明人:   ZHU Y, GAO H, WANG B, ZHANG T
  • 专利权人:   CHINA PETROLEUM CHEM CORP SINOPEC, CHINA PETROLEUM CHEM CORP
  • 国际专利分类:   H01M010/0525, H01M004/131, H01M004/1391, H01M004/485, H01M004/505, H01M004/525, H01M004/62
  • 专利详细信息:   CN114649531-A 21 Jun 2022 H01M-004/62 202277 Chinese
  • 申请详细信息:   CN114649531-A CN11506787 18 Dec 2020
  • 优先权号:   CN11506787

▎ 摘  要

NOVELTY - A modified electrode comprises an electrode, and a modified layer, which is located on the surface of the electrode having a thickness of ≯ 150 microns, comprises a composite oxide of lithium and metal, which is aluminum, titanium, zirconium, tungsten, tantalum, and/or hafnium, and has a thickness of 25-50 nm. USE - The modified electrode is useful for lithium-ion battery (claimed) used in consumer electronics, intelligent robot and electric vehicle. ADVANTAGE - The modified electrode can reduce the increase rate of the internal resistance and improve the cycle performance of the battery. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of the modified electrode, which involves: (1) uniformly mixing the electrode with 1-methyl-2-pyrrolidone to obtain a mixed slurry, coating on a surface of an aluminum foil, drying, and rolling to obtain an electrode with an unmodified surface; (2) performing surface modification on the electrode by placing the electrode in a reaction chamber, and heating the electrode by taking hot inert gas as a medium, depositing the modified layer on the surface of the electrode by atomic layer deposition, introducing a gas-phase precursor of the metal into the reaction chamber by using a carrier gas in a pulse form, introducing inert gas for cleaning, introducing an oxygen source into the reaction chamber by using carrier gas in a pulse mode, introducing inert gas for cleaning, and obtaining the modified electrode intermediate until the thickness of preset modified layer is reached; and (3) heating the modified electrode intermediate to 300-500℃ for 0.5-2 hours.