• 专利标题:   Composite water-based epoxy resin doped with modified graphene oxide comprises acid chlorinated graphene oxide, epoxy resin, p-aminobenzoic acid, N,N-dimethylethanolamine, ethylene glycol monobutyl ether and water.
  • 专利号:   WO2020082297-A1
  • 发明人:   LI W, XU Z
  • 专利权人:   SUZHOU JIREN HIGHTECH MATERIALS CO LTD
  • 国际专利分类:   C08K003/04, C08L063/00
  • 专利详细信息:   WO2020082297-A1 30 Apr 2020 C08L-063/00 202039 Pages: 12 Chinese
  • 申请详细信息:   WO2020082297-A1 WOCN111890 25 Oct 2018
  • 优先权号:   WOCN111890

▎ 摘  要

NOVELTY - Composite water-based epoxy resin doped with modified graphene oxide comprises 0.1-1 wt.% acid chlorinated graphene oxide, 20-40 wt.% epoxy resin, 12-24 wt.% p-aminobenzoic acid, 4-8 wt.% N,N-dimethylethanolamine, 10-20 wt.% ethylene glycol monobutyl ether and 30-40 wt.% water. The composite water-based epoxy resin doped with modified graphene oxide is prepared by heating epoxy resin to 70-130 degrees C to melt and dilute, adding acid chlorinated graphene oxide, stirring at high speed for 2-8 hours, then controlling the temperature at 120-140 degrees C, adding ethylene glycol monobutyl ether, stirring for 5-30 minutes, then adding p-aminobenzoic acid and continuously reacting for 6 to 10 hours, then lowering the temperature to 70-90 degrees C, adding N,N-dimethylethanolamine dropwise, and reacting for 30-60 minutes, then adding the resulting product is with water and dispersing at high speed to obtain a composite water-based epoxy resin doped with modified graphene oxide. USE - Used as composite water-based epoxy resin doped with modified graphene oxide. ADVANTAGE - The method has mild reaction and controllable reaction process, saves energy and is environmentally friendly. DETAILED DESCRIPTION - Composite water-based epoxy resin doped with modified graphene oxide comprises 0.1-1 wt.% acid chlorinated graphene oxide, 20-40 wt.% epoxy resin, 12-24 wt.% p-aminobenzoic acid, 4-8 wt.% N,N-dimethylethanolamine, 10-20 wt.% ethylene glycol monobutyl ether and 30-40 wt.% water. The composite water-based epoxy resin doped with modified graphene oxide is prepared by heating epoxy resin to 70-130 degrees C to melt and dilute, adding acid chlorinated graphene oxide, stirring at high speed for 2-8 hours while the acid chlorinated graphene oxide is dispersed to react with the epoxy resin, then controlling the temperature at 120-140 degrees C, adding ethylene glycol monobutyl ether, stirring for 5-30 minutes, then adding p-aminobenzoic acid and continuously reacting for 6 to 10 hours, then lowering the temperature to 70-90 degrees C, adding N,N-dimethylethanolamine dropwise, and reacting for 30-60 minutes, then adding the resulting product is with water and dispersing at high speed to obtain a composite water-based epoxy resin doped with modified graphene oxide.