• 专利标题:   Preparation of polylactic acid and graphene oxide composite involves using L-lactic acid and graphene oxide nanosheets to prepare polylactic acid composites by melt polycondensation, reducing graphene oxide to graphene, transforming defective crystals into stable crystals, and forming composites.
  • 专利号:   CN114621418-A
  • 发明人:   HU Z, WEI A
  • 专利权人:   NANJING POLYTECHNIC INST
  • 国际专利分类:   C08G063/08, C08G063/78, C08K003/04
  • 专利详细信息:   CN114621418-A 14 Jun 2022 C08G-063/08 202272 Chinese
  • 申请详细信息:   CN114621418-A CN11453537 12 Dec 2020
  • 优先权号:   CN11453537

▎ 摘  要

NOVELTY - Preparation of polylactic acid and graphene oxide composite material involves using graphene oxide (GO) and reduced graphene oxide films having great application prospects based on the special characteristics of graphene, L-lactic acid and graphene oxide nanosheets as raw materials to prepare polylactic acid composites by in-situ melt polycondensation, in which the weight-average molecular weight and number-average molecular weight of the composites also decrease, as the content of GO nanosheets increases, reducing portion of the graphene oxide to graphene in the process of melt polymerization from oligomers to high polymers, in which there is also a strong interaction between the GO and PLA interface, transforming some of the defective crystals into more stable crystals during the melting process, forming composites crystallize by GO nanosheets as a nucleating agent in the polymer at low temperature, in which the greater its content and the greater the crystallinity of the composite. USE - Preparation of polylactic acid and graphene oxide composite material. ADVANTAGE - The method is simple technique, low reaction temperature reaction time, and provides high yield of the product with high purity. DETAILED DESCRIPTION - Preparation of polylactic acid and graphene oxide composite material involves using graphene oxide (GO) and reduced graphene oxide films having great application prospects based on the special characteristics of graphene, L-lactic acid and graphene oxide nanosheets as raw materials to prepare polylactic acid composites by in-situ melt polycondensation, in which the weight-average molecular weight and number-average molecular weight of the composites also decrease, as the content of GO nanosheets increases, reducing portion of the graphene oxide to graphene in the process of melt polymerization from oligomers to high polymers, in which there is also a strong interaction between the GO and PLA interface, transforming some of the defective crystals into more stable crystals during the melting process, forming composites crystallize by GO nanosheets as a nucleating agent in the polymer at low temperature, in which the greater its content and the greater the crystallinity of the composite. The addition of GO nanosheets has no obvious effect on the chemical structure of PLA.