• 专利标题:   Star-type sulfonic acid zwitterionic compound as graphene dispersant, is prepared by adding trimethylolpropane-three to methylamine or ethylamine aqueous solution, and 3-aziridine propionate reaction solution in presence of acidic catalyst.
  • 专利号:   CN108546241-A
  • 发明人:   WANG C, YANG T, XIN Y, WANG X, YANG X, FEI G
  • 专利权人:   UNIV SHAANXI SCI TECHNOLOGY
  • 国际专利分类:   C01B032/194, C07C303/32, C07C309/14
  • 专利详细信息:   CN108546241-A 18 Sep 2018 C07C-309/14 201874 Pages: 9 Chinese
  • 申请详细信息:   CN108546241-A CN10271123 29 Mar 2018
  • 优先权号:   CN10271123

▎ 摘  要

NOVELTY - Star-type sulfonic acid zwitterionic compound is represented by (I). USE - Star-type sulfonic acid zwitterionic compound as graphene dispersant (claimed). DETAILED DESCRIPTION - Star-type sulfonic acid zwitterionic compound is represented by formula (I). R1=CH3 or CH2CH3. An INDEPENDENT CLAIM is included for a method for producing star-type sulfonic acid zwitterionic compound, which involves: (A) adding trimethylolpropane-three to a methylamine or ethylamine aqueous solution, and 3-aziridine propionate reaction solution in presence of an acidic catalyst for aziridine ring-opening reaction, reacting at 40-70 degrees C for 5-7 hours under weakly basic conditions; (B) adding 2-chloroethyl to the above reaction until sodium sulfonate aqueous solution is subjected to sulfonic acid group substitution and quaternization reaction, and reacting at 70-90 degrees C for 10-14 hours; (C) removing insoluble matter, concentrating reaction liquid, and purifying product by using toluene column chromatography; and (D) drying under vacuum to obatin desired product.