• 专利标题:   Preparing graphene-doped ruthenium(IV) oxide-based porous electrode comprises e.g. blasting titanium plate or foam nickel matrix, rinsing with deionized water, adding acidified graphene, and mixing with metal oxide precursor.
  • 专利号:   CN107275568-A
  • 发明人:   SHAO Y, HE J, ZHANG S, HUANG S, WANG Y
  • 专利权人:   UNIV FUZHOU
  • 国际专利分类:   H01M004/02, H01M004/04, H01M004/48, H01M004/583
  • 专利详细信息:   CN107275568-A 20 Oct 2017 H01M-004/02 201773 Pages: 6 Chinese
  • 申请详细信息:   CN107275568-A CN10536480 04 Jul 2017
  • 优先权号:   CN10536480

▎ 摘  要

NOVELTY - Preparing graphene-doped ruthenium(IV) oxide-based porous electrode comprises e.g. blasting titanium plate or foam nickel matrix, degreasing, etching, rinsing with deionized water, then adding into the ethanol solution, adding acidified graphene into a ruthenium trichloride solution, and continuing ultrasonic oscillation, and mixing graphene-added ruthenium trichloride solution and non-precious metal oxide precursor ultrasonically, drying under infrared lamp, placing at 300 degrees C in a muffle furnace for pre-oxidization for 10 minutes, and air cooling to obtain final product. USE - The method is useful for preparing graphene-doped ruthenium(IV) oxide-based porous electrode (claimed). DETAILED DESCRIPTION - Preparing graphene-doped ruthenium(IV) oxide-based porous electrode comprises (i) blasting TA2 titanium plate or foam nickel matrix, degreasing, etching, rinsing with deionized water, then adding into the ethanol solution, (ii) dissolving 0.2-0.6 mg/cm2 ruthenium loaded ruthenium trichloride in anhydrous ethanol completely by ultrasonic vibration, (iii) taking 0.2-0.6 g/cm2 graphene and acidifying with graphene by adding 0.5 ml/cm2 concentrated hydrochloric acid, and mixing the acidified graphene into a ruthenium trichloride solution, and continuing ultrasonic oscillation, (iv) dissolving precursor of the non-precious metal oxide in a molar ratio of precious metal ions to non-precious metal ions of 1:4-4:1 in anhydrous ethanol or n-butanol alcohol solution, (v) mixing the graphene-added ruthenium trichloride solution and non-precious metal oxide precursor ultrasonically with shaking until completely dissolved into a coating solution having a metal ion concentration of 30 wt.%, and (vi) coating the coating liquid on the titanium plate or the foam nickel, drying under infrared lamp, placing at 300 degrees C in a muffle furnace for pre-oxidization for 10 minutes, and air cooling until all the liquid is exhausted, and reacting at 300-380 degrees C for 1-6 hours to obtain final product.