• 专利标题:   Graphene/ceramic composite particles used for injection molding to control dispersion range and effect of graphene in matrix, are prepared by taking ceramic particles and coating e.g. aqueous polyurethane resin- and graphene powder-layer.
  • 专利号:   CN110526695-A
  • 发明人:   WU H, GAO J, FAN X, WANG J, YE X, YE Y, YUAN Y, LI B
  • 专利权人:   UNIV CHINA THREE GORGES
  • 国际专利分类:   B01J013/02, B01J013/22, C04B035/14, C04B035/628
  • 专利详细信息:   CN110526695-A 03 Dec 2019 C04B-035/14 201999 Pages: 8 Chinese
  • 申请详细信息:   CN110526695-A CN10860102 11 Sep 2019
  • 优先权号:   CN10860102

▎ 摘  要

NOVELTY - Graphene/ceramic composite particles are prepared by taking ceramic particles as core particles, and sequentially coating an aqueous polyurethane resin layer, a graphene powder layer and an alcohol-soluble resin layer to form particles having a spherical structure. The thickness of the aqueous polyurethane resin layer is 5-15 mu m. The thickness of the graphene powder layer is 0.15-0.75 mu m. The thickness of the alcohol-soluble resin layer is 5-20 mu m. USE - The graphene/ceramic composite particles are useful for injection molding to control the dispersion range and dispersion effect of graphene in the matrix. ADVANTAGE - The graphene/ceramic composite particles have the same size and excellent fluidity, and can be prepared by a simple method with low cost and high efficiency and without any pollution. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of the graphene/ceramic composite particles, which involves: (1) sieving the ceramic powder to obtain ceramic fine particles having a particle size of 200-1250 mesh; (2) adopting a boiling spray coating and drying method to uniformly coat the aqueous polyurethane resin solution on the ceramic particles to obtain aqueous polyurethane resin/ceramic composite particles; (3) performing low-temperature plasma surface treatment on the aqueous polyurethane resin/ceramic composite particles to obtain aqueous polyurethane resin/ceramic composite particles; (4) ball milling graphene powder and aqueous polyurethane resin/ceramic composite particles according to a ball mass ratio of 5:(1-2) at 250-300 rpm for 1-3 hours to obtain graphene powder/aqueous polyurethane resin/ceramic composite particles; and (5) using the boiling spray coating and drying method to uniformly coat the alcohol-soluble resin coating liquid on the graphene powder/aqueous polyurethane resin/ceramic composite particles obtained in step (4).