• 专利标题:   Functional polyelectrolyte/graphene oxide multilayer film useful as sensing coating for e.g. identifying and detecting trace heavy metal ions in water, comprises polymer/inorganic hybrid multilayer film structural material.
  • 专利号:   CN108380187-A
  • 发明人:   CAO Z, LIU G, LI D, HUANG J, ZHANG C, CHEN Y, LIU C, WU D, CHENG J
  • 专利权人:   UNIV CHANGZHOU
  • 国际专利分类:   B01J020/26, B01J020/28, B01J020/30, C02F001/28, C02F101/20
  • 专利详细信息:   CN108380187-A 10 Aug 2018 B01J-020/26 201871 Pages: 13 Chinese
  • 申请详细信息:   CN108380187-A CN10190054 08 Mar 2018
  • 优先权号:   CN10190054

▎ 摘  要

NOVELTY - A functional polyelectrolyte/graphene oxide multilayer film comprises polymer/inorganic hybrid multilayer film structural material, which is obtained by layer-by-layer self-assembly depositing branched polyethylenimine and functionalized modified graphene on surface of substrate. The branched polyethylenimine and functionalized modified graphene are self-assembled into multilayer film by electrostatic interaction and hydrogen bonding. The multilayer film structure comprises functional group capable of complexing with heavy metal ions. USE - Functional polyelectrolyte/graphene oxide multilayer film is useful as sensing coating for identifying and detecting trace heavy metal ions in water and preparing chemical sensor using quartz crystal microbalance technique (claimed). ADVANTAGE - The functional polyelectrolyte/graphene oxide multilayer film has high selectivity and excellent electrostatic effect. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation of functional polyelectrolyte/graphene oxide multilayer film, which involves weighing small molecule (A), complexing group, amino group, 0.125-0.5 g/l graphene oxide, 82 mg 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide hydrochloride as catalyst and 49.2 mg N-hydroxysuccinimide, dispersing in 20 ml deionized water, immersing substrate in polyethylenimine aqueous solution and then washing using deionized water and drying.