• 专利标题:   Method for hydro-thermal synthesis of nitrogen-doped graphene supported cobalt oxide reduction reaction catalyst for oxygen reduction, involves mixing graphene oxide with urea and cobalt salt, and subjecting to hydrothermal reduction.
  • 专利号:   CN106450354-A, CN106450354-B
  • 发明人:   ZHAI L, WANG R, SUN M, DI L
  • 专利权人:   UNIV HEFEI TECHNOLOGY, UNIV HEFEI TECHNOLOGY
  • 国际专利分类:   H01M004/90
  • 专利详细信息:   CN106450354-A 22 Feb 2017 H01M-004/90 201723 Pages: 6 Chinese
  • 申请详细信息:   CN106450354-A CN10873701 30 Sep 2016
  • 优先权号:   CN10873701

▎ 摘  要

NOVELTY - A nitrogen-doped graphene supported cobalt oxide reduction reaction catalyst hydro-thermal synthesis method involves mixing graphene oxide with urea, heating the mixture, crushing graphene oxide and adding deionized water, followed by dispersing the mixture, adding cobalt salt into a hydrothermal reaction kettle, stirring and dispersing, sealing the reaction kettle, subjecting to hydro-thermal reaction, adding hydrazine hydrate and ammonia water to adjust the pH, subjecting to hydrothermal reduction reaction, cooling the solution, and washing and drying to obtain the finished product. USE - Method for hydro-thermal synthesis of nitrogen-doped graphene supported cobalt oxide reduction reaction catalyst that is utilized as electro-catalyst for oxygen reduction. DETAILED DESCRIPTION - A nitrogen-doped graphene supported cobalt oxide reduction reaction catalyst hydro-thermal synthesis method involves mixing graphene oxide with urea, heating the mixture in an oven for heat treatment, crushing graphene oxide to 100 meshes and adding deionized water, followed by dispersing the mixture ultrasonically for 0.5 hours, adding cobalt salt into a hydrothermal reaction kettle, stirring and dispersing it uniformly, sealing the reaction kettle at 140-200 degrees C, subjecting to hydro-thermal reaction for 4-24 hours, adding hydrazine hydrate and ammonia water to adjust the pH value of solution to be 10, sealing the reaction kettle, subjecting to hydrothermal reduction reaction at 110-180 degrees C for 4-24 hours, cooling the solution by decompressing and filtering, washing with de-ionized water and absolute ethyl alcohol, and drying to obtain the finished product.