• 专利标题:   Composition useful in electrode and lithium or sulfur battery comprises nanoparticulate spheres having lithium sulfide with embedded graphene oxide.
  • 专利号:   WO2016025552-A1, KR2017042615-A, EP3180289-A1, US2017233250-A1, CN107112520-A, JP2017531284-W
  • 发明人:   CAIRNS E J, HWA Y
  • 专利权人:   UNIV CALIFORNIA
  • 国际专利分类:   C01B017/22, C01B031/04, H01M010/00, H01M004/58, C01B017/24, C01B032/10, C01B032/182, H01M010/052, H01M004/136, H01M004/36, H01M004/62, H01M004/38, H01M010/0525, C01B032/198
  • 专利详细信息:   WO2016025552-A1 18 Feb 2016 C01B-031/04 201617 Pages: 47 English
  • 申请详细信息:   WO2016025552-A1 WOUS044772 12 Aug 2015
  • 优先权号:   US036390P, US15502571

▎ 摘  要

NOVELTY - Composition comprises nanoparticulate spheres having lithium sulfide with embedded graphene oxide. USE - The composition is useful for an electrode and lithium or sulfur battery (all claimed). ADVANTAGE - The composition provides lithium/sulfur cell: having high theoretical specific energy of 2680 Wh/kg; that can be paired with different kinds of lithium metal free metals such as high capacity silicon anode; allows modifications at higher temperature and provides stable surface coating; that overcomes large volume change during cycling, polysulfide dissolution into organic electrolytes and low electrical conductivity of sulfur; that has reduced electrode resistance; having a short solid-state lithium diffusion pathway and structural stability of the carbon shell during cycling; that creates void space within the carbon shell during charge, which provide enough space to accommodate the volume expansion of up to 80% during discharge, thus better structural stability of the carbon shell can be secured because the carbon shell will not need to expand during cycling; and having graphene oxide particles that act as a second inhibitor for polysulfide dissolution due to its sulfur immobilizing nature even if some percentage of the carbon shells is broken due to physical imperfections. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are also included for: (1) synthesizing the lithium sulfide-graphene oxide composite material comprising adding a first solution comprising elemental sulfur in a non-polar organic solvent to a second solution comprising dispersed graphene oxide in a dispersing solvent and adding a strong lithium based reducing agent to make a reaction mixture, and precipitating the lithium sulfide with embedded graphene oxide material from the reaction mixture by heating the reaction mixture at elevated temperature for 2-30 minutes; and (2) the lithium sulfide-graphene oxide or graphene oxide coated with a conformal carbon layer material made by the method as above per se.