• 专利标题:   Preparation of 2, 5-furan dicarboxylic acid involves reacting 5-hydroxymethyl furfural with oxygen in mixed solvent composed of organic solvent and water in presence of oxidation catalyst containing supported metal catalyst.
  • 专利号:   CN115724813-A
  • 发明人:   ZONG B, DU Z, CHEN G, ZHENG L, SUN Q
  • 专利权人:   RES INST PETROLEUM PROCESSING SINOPEC, CHINA PETROLEUM CHEM CORP
  • 国际专利分类:   B01J023/42, B01J023/46, B01J035/10, C07D307/68
  • 专利详细信息:   CN115724813-A 03 Mar 2023 C07D-307/68 202322 Chinese
  • 申请详细信息:   CN115724813-A CN11001684 30 Aug 2021
  • 优先权号:   CN11001684

▎ 摘  要

NOVELTY - Preparation of 2, 5-furan dicarboxylic acid involves reacting 5-hydroxymethyl furfural with oxygen in mixed solvent composed of organic solvent and water in presence of oxidation catalyst. The oxidation catalyst is a supported metal catalyst containing a carrier and a metal loaded on the carrier. The metal is one or more of ruthenium or ruthenium and platinum, and palladium or gold. USE - Preparation of 2, 5-furan dicarboxylic acid. ADVANTAGE - The method is green and simple, and has high yield, uses a mixed solvent composed of water and organic solvent, which avoids the introduction of basic compounds in existing method and complicated processes such as acidification treatment, and uses a ruthenium-based catalyst supported by carbon-containing carrier with high specific surface area as oxidation catalyst, and catalyst preparation method is simple and inexpensive.