• 专利标题:   Processing technique of pulping and papermaking wastewater comprises e.g. soaking graphene oxide microsphere in tetrahydrofuran, stirring, heating to reflux, using condensed water to control reaction temperature, slowly dropping grafting agent and tetrabutylammonium bromide, reacting, and refluxing.
  • 专利号:   CN115196780-A, CN115196780-B
  • 发明人:   SUN S, HU Y, PEI X, FANG M, CHEN X, LIU W
  • 专利权人:   SHANYING INT HOLDING CO LTD
  • 国际专利分类:   C02F001/56, C02F103/28, C02F009/04, C02F001/00, C02F001/66, C02F001/72, C02F007/00, C02F009/00
  • 专利详细信息:   CN115196780-A 18 Oct 2022 C02F-009/04 202310 Chinese
  • 申请详细信息:   CN115196780-A CN10653173 09 Jun 2022
  • 优先权号:   CN10653173

▎ 摘  要

NOVELTY - Processing technique of pulping and papermaking wastewater comprises (i) soaking graphene oxide microsphere in tetrahydrofuran, stirring, heating to reflux, using condensed water to control reaction temperature at 85-90°C, slowly dropping grafting agent and tetrabutylammonium bromide, stirring, reacting for 2-3 hours, refluxing, adding self-condensation monomer and p-toluenesulfonic acid, stirring and reacting for 4-7 hours, cooling to room temperature, filtering, washing the solid by ethanol, and drying to obtain settling agent; (ii) adding settling agent to biochemically treated pulping and papermaking wastewater, stirring for 15-30 minutes, allowing to stand, precipitating, and filtering; and (iii) adjusting the filtrate pH to 2-4, adding ferrous sulfate heptahydrate and hydrogen peroxide, stirring, reacting for 30-70 minutes under aeration condition, adjusting the solution pH to 8.5-9, allowing to stand, precipitating, and filtering to obtain discharged water. USE - Processing technique of pulping and papermaking wastewater, and for useful in sewage treatment. ADVANTAGE - The processing technique has excellent impurity removing effect, flocculating multiple sedimentation effect, reduced cost of subsequent oxidation treatment process, and reduced water COD chromium (CODCr) concentration and chromaticity.