• 专利标题:   Preparing bismuth/graphene composite visible light catalyst, comprises dissolving bismuth chloride in hydrochloric acid and adding water to obtain bismuth oxychloride, and adding graphene oxide, bismuth oxychloride and hydrazine hydrate.
  • 专利号:   CN104001495-A, CN104001495-B
  • 发明人:   SU X, YAN X, CUI Y, DONG S
  • 专利权人:   UNIV HENAN NORMAL
  • 国际专利分类:   B01J023/18, C02F001/30, C02F101/38
  • 专利详细信息:   CN104001495-A 27 Aug 2014 B01J-023/18 201477 Pages: 5 Chinese
  • 申请详细信息:   CN104001495-A CN10247057 06 Jun 2014
  • 优先权号:   Y, SUN J, FENG JCN10247057

▎ 摘  要

NOVELTY - Preparing bismuth/graphene composite visible light catalyst, comprises: (a) dissolving bismuth chloride in a concentrated hydrochloric acid, and adding water and continuously stirring for 60 minutes and drying to obtain pure white bismuth oxychloride; (b) adding graphene oxide to water, ultrasonically dispersing, adding bismuth oxychloride, stirring for 2 hours, adding hydrazine hydrate and heating in a water bath to form a uniform bismuth/graphene composite; and (c) cooling the bismuth/graphene composite, filtering, washing, and drying at 60 degrees C for 8 hours. USE - The process is useful for preparing bismuth/graphene composite visible light catalyst (claimed). ADVANTAGE - The process produces bismuth/graphene composite catalyst with improved catalytic activity in visible light and stability, in environmentally friendly manner. DETAILED DESCRIPTION - Preparing bismuth/graphene composite visible light catalyst, comprises: (a) dissolving 0.73 g of bismuth chloride in 50 ml of concentrated hydrochloric acid, and adding 100 ml of water and continuously stirring for 60 minutes, filtering, washing with water and ethanol and drying to obtain pure white bismuth oxychloride; (b) adding 10-60 mg/l of graphene oxide to 100 ml of water, ultrasonically dispersing, adding 0.2 g of bismuth oxychloride, stirring for 2 hours, adding 1 ml of hydrazine hydrate, stirring and heating in a water bath at 80 degrees C to form a uniform bismuth/graphene composite; and (c) cooling the bismuth/graphene composite, filtering, washing thrice with water and ethanol, and drying at 60 degrees C for 8 hours.